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C-Homoerythrinan, 1,2-didehydro-6,7-epoxy-3,15,16-trimethoxy-, (3alpha ,6xi)-

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C-Homoerythrinan, 1,2-didehydro-6,7-epoxy-3,15,16-trimethoxy-, (3alpha ,6xi)- Basic information

Product Name:
C-Homoerythrinan, 1,2-didehydro-6,7-epoxy-3,15,16-trimethoxy-, (3alpha ,6xi)-
Synonyms:
  • C-Homoerythrinan, 1,2-didehydro-6,7-epoxy-3,15,16-trimethoxy-, (3alpha ,6xi)-
  • (6ξ)-1,2-Didehydro-6,7-epoxy-3α,15,16-trimethoxy-C-homoerythrinan
  • Wilsonine
  • 4H-Oxireno[3,3a]indolo[7a,1-a][2]benzazepine, 1a,2,5,6,11,12-hexahydro-8,9,12-trimethoxy-, (1aR,10bR,12S,14aS)-
CAS:
39024-12-9
MF:
C20H25NO4
MW:
343.42
Mol File:
39024-12-9.mol
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C-Homoerythrinan, 1,2-didehydro-6,7-epoxy-3,15,16-trimethoxy-, (3alpha ,6xi)- Chemical Properties

Melting point:
150-1°C
Boiling point:
474.8±45.0 °C(Predicted)
Density 
1.27±0.1 g/cm3(Predicted)
solubility 
Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form 
Powder
pka
6.07±0.40(Predicted)
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C-Homoerythrinan, 1,2-didehydro-6,7-epoxy-3,15,16-trimethoxy-, (3alpha ,6xi)- Usage And Synthesis

Description

This alkaloid is the major constituent of Cephalotaxus wilsoniana Hayata. When crystallized from Et2 ° it yields colourless needles. It is laevorotatory having [α]D - 36° (c 0.55, EtOH) or - 51.4° (c 0.55, CHCl3). The structure has been determined primarily from the infrared, NMR and mass spectra.

References

Powell et al., Phytochern., 11, 3317 (1972)

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