METHYL (PHENYLSULFINYL)ACETATE Chemical Properties

Melting point:

52-54 °C(lit.)

Boiling point:

130-131 °C0.5 mm Hg(lit.)

Density 

1.3339 (rough estimate)

refractive index 

1.5250 (estimate)

Flash point:

>230 °F

BRN 

1953383

Safety Information

Safety Statements 

22-24/25

WGK Germany 

3

MSDS

• Language:English Provider:SigmaAldrich

METHYL (PHENYLSULFINYL)ACETATE Usage And Synthesis

Uses

Undergoes condensation reactions with aldehydes to form vinylic sulfoxides.1

Uses

Anion of methyl 2-phenylsulfinylacetate has been employed in the synthesis of α,β-unsaturated esters.

General Description

Anion of methyl 2-phenylsulfinylacetate undergoes facile alkylative elimination under solid-liquid phase-transfer conditions to afford ring-substituted cinnamates. Methyl 2-phenylsulfinylacetate undergoes condensation reactions with aldehydes to form vinylic sulfoxides.

METHYL (PHENYLSULFINYL)ACETATE(14090-83-6)Related Product Information

• METHYL P-TOLUENESULPHONYLACETATE
• Methyl phenylsulfonylacetate
• 1-ETHOXYCARBONYL-1-TOSYLMETHYL ISOCYANIDE
• ETHYL 2-[(4-METHYLPHENYL)SULFONYL]ACETATE
• METHYL (PHENYLSULFINYL)ACETATE
• ETHYL 2-[(4-CHLOROPHENYL)SULPHONYL]ACETATE
• PHENYLSULFONYLACETIC ACID ETHYL ESTER
• TERT-BUTYL 2-[(4-CHLOROPHENYL)SULFONYL]-2-METHYLPROPANOATE
• PHENYLSULFINYLACETIC ACID ETHYL ESTER
• ETHYL 1-BENZYL-4-[(4-CHLOROPHENYL)SULFONYL]-4-PIPERIDINECARBOXYLATE
• 3-((4-CHLOROPHENYL)SULFONYL)-6,8-DIIODO-2H-CHROMEN-2-ONE
• BUTTPARK 52\04-47
• BUTTPARK 52\04-48
• 6,8-DIIODO-3-((4-(TRIFLUOROMETHOXY)PHENYL)SULFONYL)-2H-CHROMEN-2-ONE
• ETHYL 4-[(4-METHOXYPHENYL)SULFONYL]-1-(4-METHYLBENZYL)-4-PIPERIDINECARBOXYLATE
• ETHYL 1-(4-METHYLBENZYL)-4-(PHENYLSULFONYL)-4-PIPERIDINECARBOXYLATE
• ETHYL 1-(4-METHOXYBENZYL)-4-[(4-METHOXYPHENYL)SULFONYL]-4-PIPERIDINECARBOXYLATE
• ETHYL-A-(4-ACETAMIDOPHENYLSULFONYL)ACETATE