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METHYL (PHENYLSULFINYL)ACETATE

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METHYL (PHENYLSULFINYL)ACETATE Basic information

Product Name:
METHYL (PHENYLSULFINYL)ACETATE
Synonyms:
  • METHYL 2-(PHENYLSULFINYL)ACETATE
  • METHYL (PHENYLSULFINYL)ACETATE
  • methyl (phenylsulphinyl)acetate
  • methyl 2-(phenylsulphinyl)acetate
  • METHYL (+/-)-(PHENYLSULFINYL)ACETATE, 98 %
  • Acetic acid, (phenylsulfinyl)-, methyl ester
  • Methyl 2-phenylsulfinylacetate 98%
  • (Phenylsulfinyl)acetic acid methyl ester
CAS:
14090-83-6
MF:
C9H10O3S
MW:
198.24
EINECS:
237-936-6
Product Categories:
  • Organic Building Blocks
  • Sulfoxides
  • Sulfur Compounds
  • Building Blocks
  • Chemical Synthesis
  • Organic Building Blocks
  • Sulfur Compounds
Mol File:
14090-83-6.mol
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METHYL (PHENYLSULFINYL)ACETATE Chemical Properties

Melting point:
52-54 °C(lit.)
Boiling point:
130-131 °C0.5 mm Hg(lit.)
Density 
1.3339 (rough estimate)
refractive index 
1.5250 (estimate)
Flash point:
>230 °F
BRN 
1953383
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Safety Information

Safety Statements 
22-24/25
WGK Germany 
3

MSDS

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METHYL (PHENYLSULFINYL)ACETATE Usage And Synthesis

Uses

Undergoes condensation reactions with aldehydes to form vinylic sulfoxides.1

Uses

Anion of methyl 2-phenylsulfinylacetate has been employed in the synthesis of α,β-unsaturated esters.

General Description

Anion of methyl 2-phenylsulfinylacetate undergoes facile alkylative elimination under solid-liquid phase-transfer conditions to afford ring-substituted cinnamates. Methyl 2-phenylsulfinylacetate undergoes condensation reactions with aldehydes to form vinylic sulfoxides.

METHYL (PHENYLSULFINYL)ACETATESupplier

Energy Chemical
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