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ChemicalBook >  Product Catalog >  Pharmaceutical intermediates >  Heterocyclic compound >  (+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE

(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE

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(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Basic information

Product Name:
(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE
Synonyms:
  • (s,s)-4-phenyl-α-(4-phenyloxazolidin-2-ylidene)-2-oxazoline-2-acetonitrile
  • (4S)-(+)-Phenyl-alpha-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile 97%
  • (+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE
  • (S,S)-4-PHENYL-ALPHA-(4-PHENYLOXAZOLIDIN-2-YLIDENE)-2-OXAZOLINE-2-ACETONITRILE
  • (S,S)-4-phe-A-(4-phe.oxazolidin-ylidene) -oxazoline-acetonit.
  • (S,S)-(+)-4-PHENYL-ALPHA-(4-PHENYLOXAZOL IDIN-2 -YLIDENE)-2-OXAZOLINE-2-ACETONITR
  • (4s)-(+)-phenyl-α-[(4s)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile
  • (2Z)-2-[(4S)-4-phenyl-4,5-dihydro-1,3-oxazol-2-yl]-2-[(4S)-4-phenyl-1,3-oxazolidin-2-ylidene]acetonitrile
CAS:
150639-33-1
MF:
C20H17N3O2
MW:
331.37
Mol File:
150639-33-1.mol
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(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Chemical Properties

Melting point:
146-148 °C(lit.)
Boiling point:
457.5±45.0 °C(Predicted)
Density 
1.27±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
pka
3.30±0.70(Predicted)
optical activity
[α]20/D +364°, c = 1 in chloroform
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3

MSDS

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(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Usage And Synthesis

Uses

Ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.

General Description

(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile is a C2-symmetric chiral bisoxazoline (BOX) ligand.

(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILESupplier

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