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Benzyl methyl ether

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Benzyl methyl ether Basic information

Product Name:
Benzyl methyl ether
Synonyms:
  • (methoxymethyl)-benzen
  • Ether, benzyl methyl
  • Methyl benzyl ether
  • Methylbenzylether
  • (METHOXYMETHYL)BENZENE
  • BENZYL METHYL ETHER
  • 1-(METHOXYMETHYL)BENZENE
  • ALPHA-METHOXYTOLUENE
CAS:
538-86-3
MF:
C8H10O
MW:
122.16
EINECS:
208-705-7
Product Categories:
  • Ethers
  • Organic Building Blocks
  • Oxygen Compounds
Mol File:
538-86-3.mol
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Benzyl methyl ether Chemical Properties

Melting point:
-52.6 °C
Boiling point:
174 °C(lit.)
Density 
0.987 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.502(lit.)
Flash point:
53 °C
storage temp. 
Sealed in dry,Room Temperature
form 
clear liquid
color 
Colorless to Almost colorless
Odor
at 10.00 % in dipropylene glycol. fruity ethereal ylang green floral hyacinth
Odor Type
fruity
Water Solubility 
practically insoluble
Merck 
14,1140
Dielectric constant
3.5(20℃)
LogP
1.920
CAS DataBase Reference
538-86-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, (methoxymethyl)-(538-86-3)
EPA Substance Registry System
Benzyl methyl ether (538-86-3)
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Safety Information

Risk Statements 
10
Safety Statements 
16
RIDADR 
UN 3271 3/PG 3
WGK Germany 
3
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29093090

MSDS

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Benzyl methyl ether Usage And Synthesis

Chemical Properties

Colorless liquid. Sp.Gr. 0.98. B.P. 171℃. Insoluble in water, soluble in alcohol and oils.

Uses

Benzyl methyl ether is occasionally used in soap perfumes, industrial perfumes and masking odors, where power and low cost are essential.

Uses

Benzyl methyl ether is used to produce benzaldehyde. It is used as perfuming agents.

Preparation

Benzyl methyl ether is produced from Benzyl chloride and Sodium methoxide in Methanol solution.

Synthesis Reference(s)

Canadian Journal of Chemistry, 54, p. 685, 1976 DOI: 10.1139/v76-099
Chemistry Letters, 13, p. 1225, 1984
Tetrahedron Letters, 20, p. 4679, 1979

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