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4-Methoxystyrene

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4-Methoxystyrene Basic information

Product Name:
4-Methoxystyrene
Synonyms:
  • 1-Methoxy-4-vinylbenzene ,98%
  • 4-Vinylanisole, 1-Ethenyl-4-methoxybenzene
  • 4-Methoxystyrene 
  • 4-Methoxystyrene, stabilized, 96% 25GR
  • 4-Methoxystyrene, stabilized, 96% 5GR
  • Benzene,1-ethenyl-4-Methoxy-
  • 4-Methoxystyrene (stabilized with TBC), 95.0%(GC)
  • 4-Methoxystyrene, stabilized with 0.1% 4-tert-butylcatechol
CAS:
637-69-4
MF:
C9H10O
MW:
134.18
EINECS:
211-298-9
Product Categories:
  • Styrenes
  • Aromatic compound
Mol File:
637-69-4.mol
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4-Methoxystyrene Chemical Properties

Melting point:
2°C
Boiling point:
41-42 °C/0.5 mmHg (lit.)
Density 
1.009 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.562
Flash point:
170 °F
storage temp. 
Store at <= 20°C.
solubility 
Slightly miscible with methanol.
form 
Liquid
Specific Gravity
1.009
color 
Clear colorless to yellow
Odor
sweet
BRN 
1098935
LogP
2.874 (est)
CAS DataBase Reference
637-69-4(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-ethenyl-4-methoxy-(637-69-4)
EPA Substance Registry System
Benzene, 1-ethenyl-4-methoxy- (637-69-4)
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Safety Information

Safety Statements 
23-24/25
WGK Germany 
3
HS Code 
29093090

MSDS

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4-Methoxystyrene Usage And Synthesis

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

4-Methoxystyrene is employed in the ferric chloride-catalyzed addition of activated methylenes to styrenes. It acts as a monomer in polymerization reactions. Further, it is used to prepare 1,1,2,2-Tetracyano-3-(p-methoxyphenyl)cyclobutane by reacting with ethenetetracarbonitrile.

Synthesis Reference(s)

Chemistry Letters, 13, p. 1897, 1984
The Journal of Organic Chemistry, 52, p. 422, 1987 DOI: 10.1021/jo00379a020
Tetrahedron Letters, 35, p. 8773, 1994 DOI: 10.1016/S0040-4039(00)78494-2

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