BrettPhosPalladacycle
BrettPhosPalladacycle Basic information
- Product Name:
- BrettPhosPalladacycle
- Synonyms:
-
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)
- Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II),98%
- BrettPhos Pd G1 Methyl-t-Butyl Ether Adduct
- Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II), Min. 98% [BrettPhos Palladacycle]
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-aminoeth
- Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-Minoethyl)phenyl]palladiuM(II),Min.98%[BrettPhosPalladacycle]
- (BrettPhos) palladium(II) phenethylamine chloride
- BrettPhos Palladacycle
- CAS:
- 1148148-01-9
- MF:
- C43H63ClNO2PPd
- MW:
- 798.83
- Product Categories:
-
- Buchwald Ligands&Precatalysts
- Buchwald Precatalysts Series
- Pd
- Mol File:
- 1148148-01-9.mol
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BrettPhosPalladacycle Chemical Properties
- Melting point:
- 198-204 °C
- form
- Powder
- color
- white
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BrettPhosPalladacycle Usage And Synthesis
Reaction
- Catalyst for cross-coupling reactions using aryl mesylates with electron-deficient anilines.
- Catalyst for rapid C-N bond-forming processes at low catalyst loading.
- Cross-coupling of 3-Bromo-2-aminopyridine with primary amines.
Uses
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Catalyst for:
- C,N-cross coupling of unprotected 3-halo-2-aminopyridines with primary and secondary amines
- Amination reaction
- N-arylation of aminophenols
General Description
BrettPhos Pd G1 is a Buchwald first generation (G1) palladacycle precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. The formation of the active Pd(0) species in the G1 precatalyst is easy to generate, requiring merely a deprotonation with a base. The resulting catalyst is very active, even at temperatures down to ?40 °C, and can be used in a variety of cross-coupling protocols.
BrettPhosPalladacycleSupplier
J & K SCIENTIFIC LTD.
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Energy Chemical
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Accela ChemBio Co.,Ltd.
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WuHan Taiyukaishang Chemical Co., Ltd.
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- 027-87680032 18963957250
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BrettPhosPalladacycle(1148148-01-9)Related Product Information
- Chloro(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [BrettPhos Palladacycle]
- XPhos Pd G3
- SPhos Palladacycle Gen. 4
- XPhos Pd G4
- Xantphos Pd G3
- BrettPhos Pd G3
- XPhos Pd G2
- RuPhos Pd G1 Methyl t--Butyl Ether Adduct
- SPhos Pd G2
- Palladacycle Gen. 3
- t-BuXphos Palladacycle Gen. 4
- RuPhos Palladacycle Gen. 4
- t-BuBrettPhos Palladacycle Gen. 3
- SPhos Pd G3
- SPhos Pd G1, Methyl t-Butyl Ether Adduct
- RuPhos Pd G2
- tBuXPhos Pd G1
- XPhos Pd G1