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1-Chloromethyl naphthalene

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1-Chloromethyl naphthalene Basic information

Product Name:
1-Chloromethyl naphthalene
Synonyms:
  • 1-(chloromethyl)-naphthalen
  • 1-(Chloromethyl)naphthene
  • AKOS BBS-00004040
  • 1-chloromethyl-naphthalen
  • 1-Menaphthyl chloride
  • 1-menaphthylchloride
  • 1-(CHLOROMETHYL)NAPHTHALENE
  • 1-CHLOROMETHYLNAPHTHYL
CAS:
86-52-2
MF:
C11H9Cl
MW:
176.64
EINECS:
201-678-2
Product Categories:
  • API Intermediate
  • Naphthalene series
  • Aryl
  • Building Blocks
  • C9 to C12
  • Chemical Synthesis
  • Naphthalene derivatives
  • API intermediates
  • Halogenated Hydrocarbons
  • Organic Building Blocks
  • bc0001
  • 86-52-2
Mol File:
86-52-2.mol
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1-Chloromethyl naphthalene Chemical Properties

Melting point:
32 °C(lit.)
Boiling point:
291 °C
Density 
1.18 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.635(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform, Ethyl Acetate (Slightly), Methanol (Sparingly)
form 
Liquid After Melting
Specific Gravity
1.18
color 
deep brown
Water Solubility 
Insoluble in water.
Sensitive 
Moisture Sensitive
BRN 
636885
InChIKey
XMWGTKZEDLCVIG-UHFFFAOYSA-N
LogP
3.97 at 20℃
CAS DataBase Reference
86-52-2(CAS DataBase Reference)
NIST Chemistry Reference
Naphthalene, 1-(chloromethyl)-(86-52-2)
EPA Substance Registry System
Naphthalene, 1-(chloromethyl)- (86-52-2)
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Safety Information

Hazard Codes 
C,Xn
Risk Statements 
21/22-34-36/37/38-36-20/21/22
Safety Statements 
26-36/37/39-45-60-20-27
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
RTECS 
QJ2800000
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29036990

MSDS

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1-Chloromethyl naphthalene Usage And Synthesis

Chemical Properties

Solid

Uses

1-(Chloromethyl)naphthalene is a key material for synthesis dye pigment and as fluorescent brightening agent. It is employed in synthetic resin and medicine. Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives produce ortho- or para-substituted carbocycles in satisfactory to excellent yields.

General Description

Kinetics and dissociation mechanism of 1-(chloromethyl)naphthalene following 266nm photoexcitation has been studied. Intermolecular nucleophilic dearomatization of 1-chloromethyl naphthalene with various activated methylene compounds has been investigated.

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