(2-NAPHTHYL)METHYLZINC BROMIDE Chemical Properties

Density 

0.978 g/mL at 25 °C

Flash point:

-17 °C

storage temp. 

2-8°C

Safety Information

Hazard Codes 

F,Xn

Risk Statements 

14-19-22-36/38-40-36/37-11

Safety Statements 

16-26-33-36-36/37

RIDADR 

UN 2056 3/PG 2

WGK Germany 

3

(2-NAPHTHYL)METHYLZINC BROMIDE Usage And Synthesis

Uses

(2-Naphthylmethyl)zinc bromide can be used as a reagent for the synthesis of:

• 4-(5,6-dimethoxy-2-(naphthalen-2-ylmethyl)pyridin-3-yl)benzonitrile from 4-(2-bromo-5,6-dimethoxypyridin-3-yl)benzonitrile using Pd catalyst.
• (E)-stilbene, (2,2′-[1,4-phenylenedi-(1E)-2,1-ethenediyl]bis[naphthalene]) from 1,4-benzenedicarboxaldehyde in the presence of Pd catalyst and a silylating agent.

General Description

(2-Naphthylmethyl)zinc bromide is an organozinc halide, which is typically used as a reagent in Negishi cross-coupling reactions. In this process, the organozinc halide reacts with organic halides or triflates to form a carbon-carbon bond in the presence of a Pd catalyst.

(2-NAPHTHYL)METHYLZINC BROMIDE(152329-44-7)Related Product Information

• 4-METHYL-2-PYRIDYLZINC BROMIDE
• PHENETHYLZINC BROMIDE
• 4-BROMOBENZYLZINC BROMIDE
• 1-PHENYLVINYLZINC BROMIDE
• 2-CHLORO-6-FLUOROBENZYLZINC CHLORIDE
• 5-ETHOXYCARBONYL-2-METHYLFURANZINC CHLORIDE
• 2 3 4 5 6-PENTAFLUOROBENZYLZINC CHLORID&
• 2,6-DICHLOROBENZYLZINC CHLORIDE
• 2 5-DIFLUOROBENZYLZINC CHLORIDE
• 5-BROMO-2-METHOXYBENZYLZINC CHLORIDE
• 4-METHOXYBENZYLZINC CHLORIDE
• 2-THIAZOLYLZINC BROMIDE
• 1-PENTYLZINC BROMIDE
• 3,4-DIMETHOXYBENZYLZINC CHLORIDE
• 3-BROMOBENZYLZINC BROMIDE
• Zinc bromide
• BENZYLZINC BROMIDE
• (2-NAPHTHYL)METHYLZINC BROMIDE