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ETHYL 3-PHENYLGLYCIDATE

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ETHYL 3-PHENYLGLYCIDATE Basic information

Product Name:
ETHYL 3-PHENYLGLYCIDATE
Synonyms:
  • Ethyl 3-phenylglycidate,98%,mixture of cis and trans
  • Ethyl 3-phenylglycidate,90%,mixture of cis and trans
  • ethyl2,3-epoxy-3-phenylpropion
  • 3-Phenylglycidic Acid Ethyl Ester Ethyl 3-Phenyloxiranecarboxylate
  • Ethyl 3-Phenylglycidate 
  • Ethyl 3-Phenylglycidate (cis- and trans- mixture)
  • 3-phenyl-glycidicaciethylester
  • 3-phenyl-oxiranecarboxylicaciethylester
CAS:
121-39-1
MF:
C11H12O3
MW:
192.21
EINECS:
204-467-3
Product Categories:
  • -
  • Building Blocks
  • Chemical Synthesis
  • Organic Building Blocks
  • Oxygen Compounds
  • Alphabetical Listings
  • E-F
  • Flavors and Fragrances
  • Epoxides
  • Organic Building Blocks
  • Oxygen Compounds
Mol File:
121-39-1.mol
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ETHYL 3-PHENYLGLYCIDATE Chemical Properties

Boiling point:
96 °C0.5 mm Hg(lit.)
Density 
1.102 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.518(lit.)
FEMA 
2454 | ETHYL 3-PHENYLGLYCIDATE
Flash point:
>230 °F
storage temp. 
0-6°C
form 
Liquid
color 
Clear colorless to yellow
Sensitive 
Moisture Sensitive
JECFA Number
1576
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference
121-39-1(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
23-24/25
WGK Germany 
2
RTECS 
MB4970000
TSCA 
Yes
HS Code 
29189990

MSDS

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ETHYL 3-PHENYLGLYCIDATE Usage And Synthesis

Chemical Properties

pale yellow liquid

Chemical Properties

Ethyl 3-Phenylglycidate is a colorless liquid with a strawberry-like odor.
It is prepared by treating ethyl cinnamatewith peracetic acid or by condensation of benzaldehyde with ethyl chloroacetate (in the aforementioned Darzens reaction, R == H).Theglycidate is used as a long-lasting fragrancematerial for creating harmonic, fruity notes in household and fine fragrances.

Chemical Properties

Ethyl 3-phenylglycidate has a strong, fruity odor suggestive of strawberry with a corresponding sweet flavor.

Preparation

Usually prepared by the reaction of benzaldehyde and the ethyl ester of monochloracetic acid in the presence of an alkaline condensing agent; by reacting the silver salt of phenyl glycidic acid with ethyl iodide.

Aroma threshold values

Detection: 8.5 ppm

Taste threshold values

Taste characteristics at 30 ppm: sweet, fruity and berry with dried fruit and floral nuance.

General Description

Clear pale yellow or yellow liquid.

Air & Water Reactions

Slightly water soluble.

Reactivity Profile

Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

Fire Hazard

ETHYL 3-PHENYLGLYCIDATE is probably combustible.

Safety Profile

Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

ETHYL 3-PHENYLGLYCIDATESupplier

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