P-METHYLPHENYLACETALDEHYDE
P-METHYLPHENYLACETALDEHYDE Basic information
- Product Name:
- P-METHYLPHENYLACETALDEHYDE
- Synonyms:
-
- (4-Methylphenyl)acetaldehyde
- (4-methyl-phenyl)-acetaldehyde
- 4-methyl-benzeneacetaldehyd
- 4-methyl-Benzeneacetaldehyde
- 4-methyl-phenyl-acetaldehyde
- P-TOLYLACETALDEHYDE
- benzeneacetaldehyde,-methyl-
- 4-TOLYLACETALDEHYDE
- CAS:
- 104-09-6
- MF:
- C9H10O
- MW:
- 134.18
- EINECS:
- 203-173-2
- Product Categories:
-
- Aromatic Aldehydes & Derivatives (substituted)
- Aldehydes
- Benzene derivatives
- Phenyls & Phenyl-Het
- Mol File:
- 104-09-6.mol
P-METHYLPHENYLACETALDEHYDE Chemical Properties
- Melting point:
- 40°C
- Boiling point:
- 221.5°C (estimate)
- Density
- 1.0052
- refractive index
- 1.5255 (estimate)
- FEMA
- 3071 | P-TOLYLACETALDEHYDE
- storage temp.
- 2-8°C
- Odor
- at 10.00 % in dipropylene glycol. fresh sweet green cortex lilac narcissus nutty phenolic fruity cherry
- Odor Type
- green
- JECFA Number
- 1023
- LogP
- 2.24
- EPA Substance Registry System
- Benzeneacetaldehyde, 4-methyl- (104-09-6)
P-METHYLPHENYLACETALDEHYDE Usage And Synthesis
Chemical Properties
p-Tolylacetaldehyde has a powerful and refreshing green-fruity, "forest-like", sweet, floral odor of moderate tenacity. The undiluted material has a rather sharp initial odor, but sweetness predominates in the diluted product. The taste is sweet-fruity, mildly green at concentrations near 10 ppm.
Uses
4-Methylphenylacetaldehyde (p-Tolylacetaldehyde) is used in perfumes, e.g., in soap, in tobacco fragrances, in the preparation of pesticides, etc.
Preparation
From p-methylbenzaldehyde; also from p-methylbenzyl chloride and hexamethylene tetramine.The methods of preparation correspond closely to those of phenylacetaldehyde. Thus, the compound can be prepared by glycidic ester synthesis from 4-methylbenzaldehyde and chloroacetate ester, by hydroformylation of 4-methylbenzylhalide with Co2(CO)8Na2CO3 in acetonitrile, or by oxidation of 4-methylstyrene.
Production Methods
p-Tolylacetaldehyde can be produced 1) from para-Methylbenzaldehyde via Darzen's reaction. 2) from para-Methylbenzy lchloride plus Hexamethyiene tetramine.
Definition
ChEBI: (4-Methylphenyl)acetaldehyde is a member of phenylacetaldehydes.
Taste threshold values
Taste characteristics at 10 ppm: sweet, fruity cherry with spicy an nutty nuances.
Synthesis Reference(s)
Synthetic Communications, 17, p. 677, 1987 DOI: 10.1080/00397918708075741
P-METHYLPHENYLACETALDEHYDESupplier
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P-METHYLPHENYLACETALDEHYDE(104-09-6)Related Product Information
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- 4-(BROMOMETHYL)PHENYLACETIC ACID
- 4-(TRIFLUOROMETHYL)MANDELIC ACID
- MESITYLACETIC ACID
- 4-Methylphenylacetic acid
- 4,4'-DIMETHYLBENZIL
- 1,4-Phenylenediacetic acid
- ETHYL P-TOLYLACETATE
- 4-(Trifluoromethyl)phenylacetic acid
- 4-Biphenylacetic acid
- 3,4-xylylacetaldehyde
- 2,4-dimethylphenylacetaldehyde
- A-METHYLPHENYLACETALDEHYDE,METHYLPHENYLACETALDEHYDE,alpha-Methylphenylacetaldehyde
- 3-(2-FURYL)-2-PHENYLPROPENAL