[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Chemical Properties

Melting point:

360 °C

storage temp. 

Inert atmosphere,Room Temperature

form 

Powder

color 

off-white

Water Solubility 

insoluble

Sensitive 

Moisture sensitive

InChI

InChI=1S/C26H24P2.2ClH.Pd/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

InChIKey

LDJXFZUGZASGIW-UHFFFAOYSA-L

SMILES

C(P(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1.[Pd](Cl)Cl

CAS DataBase Reference

19978-61-1(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-37/39

WGK Germany 

3

HS Code 

28439000

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Usage And Synthesis

Chemical Properties

orange powder

Uses

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) is a precatalyst used in the production of acrylic acid sodium salt via coupling of CO2 with ethene.
suzuki reaction.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium

Precautions

This palladium catalyst, also known as [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II), presents as a very pale yellow to yellow crystalline powder. Store under inert gas, at ambient temperatures and protected from moisture. This substance is moisture sensitive. [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride is incompatible with oxidizing agents. This chemical is harmful if swallowed, in contact with skin or if inhaled. It causes skin irritation as well as serious eye irritation.

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)(19978-61-1)Related Product Information

• ETHANE
• 1,5-Diphenylcarbazide
• Hexafluoroethane
• Palladium
• Diphenylsilane
• Diphenylphosphine
• Palladium chloride
• Chlorodiphenylphosphine
• 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride
• 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
• Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
• DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II)
• Dichloro(2-pyridinecarboxylato)gold
• Dichloro(1,5-cyclooctadien)ruthenium(II) polymer
• Tetrakis(triphenylphosphine)platinum
• [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
• Bis(tricyclohexylphosphine)palladium(II) Dichloride
• Bis(benzonitrile)palladium chloride