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Bis(2-nitrophenyl) disulfide

Basic information Safety Supplier Related

Bis(2-nitrophenyl) disulfide Basic information

Product Name:
Bis(2-nitrophenyl) disulfide
Synonyms:
  • O-NITROPHENYLDISULFIDE
  • O,O'-DINITROPHENYL DISULFIDE
  • Bis-(2-nitrophenyl)-disulfid
  • Disulfide, bis(2-nitrophenyl)
  • Disulfide, bis(o-nitrophenyl)
  • Disulfide,bis(2-nitrophenyl)
  • o,o'-Dinitrodiphenyl disulfide
  • 1-Nitro-2-[(2-nitrophenyl)disulfanyl]benzene
CAS:
1155-00-6
MF:
C12H8N2O4S2
MW:
308.33
EINECS:
214-581-5
Mol File:
1155-00-6.mol
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Bis(2-nitrophenyl) disulfide Chemical Properties

Melting point:
194-197 °C (lit.)
Boiling point:
441.9±30.0 °C(Predicted)
Density 
1.62 g/cm3 (-123.16℃)
refractive index 
1.6510 (estimate)
storage temp. 
Sealed in dry,Room Temperature
form 
powder to crystal
color 
Light yellow to Brown
BRN 
1016770
CAS DataBase Reference
1155-00-6(CAS DataBase Reference)
NIST Chemistry Reference
Bis(o-nitrophenyl)disulfide(1155-00-6)
EPA Substance Registry System
Disulfide, bis(2-nitrophenyl) (1155-00-6)
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Safety Information

Safety Statements 
22-24/25
WGK Germany 
3
TSCA 
Yes
HS Code 
29309099

MSDS

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Bis(2-nitrophenyl) disulfide Usage And Synthesis

Chemical Properties

yellow to yellow-green crystalline powder

Uses

Bis(o-Nitrophenyl) Disulfide, can be used in a PVC membrane electrode as a sensor for zinc ions. It is also a building block used for the synthesis of various pharmaceutical compounds. It can be used for the preparation of a series of 4-Azaindole inhibitors of c-Met kinase.

General Description

PVC membrane electrode based on bis(2-nitrophenyl)disulfide carrier acts as sensor for zinc ions. Bis(2-nitrophenyl) disulphide undergoes mechanochemical grinding with bis(4-chlorophenyl)disulfide in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene catalyst via metathesis reaction to yield non-symmetrical heterodimer 4-chlorophenyl-2′-nitrophenyl disulfide.

Purification Methods

Purify the disulfide by recrystallisation from glacial AcOH or from *C6H6 and the yellow needles are dried in an oven at 100o until the odour of the solvent is absent. It is sparingly soluble in EtOH and Me2CO. [Bogert & Stull Org Synth Coll Vol I 220 1941, Bauer & Cymerman J Chem Soc 3434 1949, Beilstein 6 IV 1672.]

Bis(2-nitrophenyl) disulfide Preparation Products And Raw materials

Raw materials

Preparation Products

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