TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II) Chemical Properties

Melting point:

230°C

storage temp. 

Inert atmosphere,Room Temperature

form 

crystal

color 

yellow

InChI

1S/2C21H20P.2C2H4O2.2Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;2*1-2(3)4;;/h2*4-15H,1H2,2-3H3;2*1H3,(H,3,4);;/q;;;;2*+1/p-2

InChIKey

DUHUARWWBNTVDI-UHFFFAOYSA-L

SMILES

CC(=O)O[Pd]Cc1ccccc1P(c2ccccc2C)c3ccccc3C.CC(=O)O[Pd]Cc4ccccc4P(c5ccccc5C)c6ccccc6C

Safety Information

Risk Statements 

36/37/38

Safety Statements 

26-36/37/39

WGK Germany 

3

HS Code 

28439000

Storage Class

11 - Combustible Solids

MSDS

• Language:English Provider:ALFA

TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II) Usage And Synthesis

Reaction

Heck olefination of haloarenes.

Chemical Properties

Yellow powder

Uses

trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II) is a useful catalyst for C-C and C-N cross coupling reaction.

Uses

Homogeneous catalyst in carbon-carbon bond forming reactions such as the Heck and Suzuki reactions.

General Description

sold in collaboration with Solvias AG

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium
reagent type: ligand
reaction type: Asymmetric synthesis

TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)(172418-32-5)Related Product Information

• DIPHENYL(O-TOLYL)PHOSPHINE
• BIS(O-TOLYL)PHOSPHINE
• Tri(o-tolyl)phosphine
• TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)