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1,1-DIMETHOXYCYCLOHEXANE

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1,1-DIMETHOXYCYCLOHEXANE Basic information

Product Name:
1,1-DIMETHOXYCYCLOHEXANE
Synonyms:
  • 1,1-DIMETHOXYCYCLOHEXANE
  • Cyclohexanone dimethyl ketal 99%
  • TIMTEC-BB SBB008403
  • CYCLOHEXANONE DIMETHYL ACETAL
  • CYCLOHEXANONE DIMETHYL KETAL
  • DIMETHOXYCYCLOHEXANE
  • 1,1-Dimethoxycyclohexane >
  • Cyclohexane, 1,1-dimethoxy-
CAS:
933-40-4
MF:
C8H16O2
MW:
144.21
Mol File:
933-40-4.mol
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1,1-DIMETHOXYCYCLOHEXANE Chemical Properties

Boiling point:
83 °C/50 mmHg (lit.)
Density 
0.948 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.439(lit.)
Flash point:
50°C
solubility 
Chloroform (Soluble), Ethyl Acetate (Slightly)
form 
clear liquid
color 
Colorless to Yellow
CAS DataBase Reference
933-40-4(CAS DataBase Reference)
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Safety Information

Risk Statements 
10-18
Safety Statements 
16-51
RIDADR 
3271
WGK Germany 
3
HS Code 
2911.00.5000
HazardClass 
3
PackingGroup 
III
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1,1-DIMETHOXYCYCLOHEXANE Usage And Synthesis

Uses

1,1-Dimethoxycyclohexane is a useful research chemical used in the preparation of N-??substituted valiolamine derivatives as potential oral antidiabetic agents.

Synthesis Reference(s)

Canadian Journal of Chemistry, 61, p. 366, 1983 DOI: 10.1139/v83-065
Tetrahedron Letters, 30, p. 6151, 1989 DOI: 10.1016/S0040-4039(01)93328-3

General Description

Cyclohexanone dimethyl ketal reacts with trimethylsilane in the presence of trimethylsilyl triflate to form the corresponding ether. It can also undergo allylation and propargylation in the presence of indium to form the corresponding homoallylic or homopropargylic alcohol, respectively.

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