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5-METHYL-DL-TRYPTOPHAN

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5-METHYL-DL-TRYPTOPHAN Basic information

Product Name:
5-METHYL-DL-TRYPTOPHAN
Synonyms:
  • TIMTEC-BB SBB003368
  • 5-METHYL-DL-TRYPTOPHAN
  • H-Trp(5-Me)-OH
  • H-5-ME-DL-TRP-OH
  • DL-2-AMINO-3-(5-METHYLINDOLYL)PROPIONIC ACID
  • DL-5-METHYLTRYPTOPHAN
  • 5-Methyl-DL-tryptophan,98%
  • 5-METHYL-DL-TRYPTOPH
CAS:
951-55-3
MF:
C12H14N2O2
MW:
218.25
EINECS:
213-453-6
Product Categories:
  • Amino Acids
  • Biochemistry
  • Biological-modified Amino Acids
  • Indoles
  • Tryptophans
  • Amino acids methyl、ethyl、t-butyl series
  • Indoles and derivatives
  • I - ZPeptide Synthesis
  • Tryptophan Derivatives
  • Amino Acids
  • Modified Amino Acids
  • Unnatural Amino Acid Derivatives
  • Peptide Synthesis
Mol File:
951-55-3.mol
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5-METHYL-DL-TRYPTOPHAN Chemical Properties

Melting point:
~275 °C (dec.)
Boiling point:
358.94°C (rough estimate)
alpha 
[α]D20 -1~+1゜ (c=1, dil. HCl)
Density 
1.1402 (rough estimate)
refractive index 
1.6660 (estimate)
storage temp. 
Sealed in dry,Room Temperature
form 
Powder
pka
2.26±0.10(Predicted)
color 
Off-white
BRN 
20225
CAS DataBase Reference
951-55-3(CAS DataBase Reference)
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Safety Information

Safety Statements 
22-24/25
WGK Germany 
3
8
HS Code 
29339900

MSDS

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5-METHYL-DL-TRYPTOPHAN Usage And Synthesis

Chemical Properties

off-white powder

Definition

ChEBI: 5-methyltryptophan is a tryptophan derivative that is tryptophan substituted by a methyl group at position 5 of the indole ring. It is a non-proteinogenic alpha-amino acid and a tryptophan derivative.

Purification Methods

Crystallise dl-5-methyltryptophan from aqueous EtOH after dissolving it in aqueous NaOH, precipitating with AcOH, filtering the solid off and drying for 24hours at 50o. [Jackman & Archer J Am Chem Soc 68 2105 1946, Beilstein 22 IV 6815.] The picrate crystallises from MeOH with m 202o(dec). The N-phenylcarbamoyl derivative crystallises from aqueous MeOH with m 202o. [Gordon & Jackson J Biol Chem 110 151, 154 1935.]

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