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METHYL LINOLENATE

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METHYL LINOLENATE Basic information

Product Name:
METHYL LINOLENATE
Synonyms:
  • 12,15-Octadecatrienoicacid,methylester,(Z,Z,Z)-9
  • 15-octadecatrienoicacid,methylester,(z,z,z)-12
  • cis,cis,cis-octadeca-9,12,15-trienoicacidmethylester
  • Methyl (9Z,12Z,15Z)-9,12,15-octadecatrienoate
  • Methyl all-cis-9,12,15-octadecatrienoate
  • Methyl alpha-linolenate
  • Methyl linolenate, alpha
  • Methyl Linolenate (5 x 50 mg)
CAS:
301-00-8
MF:
C19H32O2
MW:
292.46
EINECS:
206-102-3
Product Categories:
  • Biochemistry
  • Higher Fatty Acids & Higher Alcohols
  • Unsaturated Higher Fatty Acid Esters
  • Analytical Chemistry
  • Fatty Acid Methyl Esters (GC Standard)
  • Standard Materials for GC
Mol File:
301-00-8.mol
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METHYL LINOLENATE Chemical Properties

Melting point:
-57℃
Boiling point:
182 °C/3 mmHg (lit.)
Density 
0.895 g/mL at 25 °C (lit.)
FEMA 
3411 | METHYL LINOLEATE (48%) METHYL LINOLENATE (52%) MIXTURE
refractive index 
n20/D 1.470(lit.)
Flash point:
113 °C
storage temp. 
-20°C
solubility 
Chloroform (Sparingly), Ethyl Acetate (Slightly), Methanol (Slightly)
form 
Liquid
color 
Clear colorless
JECFA Number
346
BRN 
1728194
Stability:
Light Sensitive
InChIKey
DVWSXZIHSUZZKJ-YSTUJMKBSA-N
LogP
6.96
CAS DataBase Reference
301-00-8(CAS DataBase Reference)
EPA Substance Registry System
9,12,15-Octadecatrienoic acid, methyl ester, (9Z,12Z,15Z)- (301-00-8)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
40-67-36/37/38
Safety Statements 
23-24/25-36/37-26
RIDADR 
UN 1593 6.1/PG 3
WGK Germany 
1
HS Code 
29161500

MSDS

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METHYL LINOLENATE Usage And Synthesis

Chemical Properties

clear colorless liquid

Occurrence

Reported found in banana, grape, grapefruit juice, melon, strawberries, mushroom and cassava.

Uses

Methyl Linolenate has potential application towards human lung carcinoma cell lines, displaying cytotoxicity. Essential oil component.

Definition

ChEBI: Methyl linolenate is a fatty acid methyl ester derived from alpha-linolenic acid. It has a role as a plant metabolite and an insect attractant. It is functionally related to an alpha-linolenic acid.

Chemical Reactivity

Methyl linolenate has two bis-allylic methylene groups and reacts twice as fast with oxygen as linoleate. Linoleate was 40 times more reactive than oleate, and linolenate was 2.4 times more reactive than linoleate. The two bis-allylic methylene groups in linolenate act independently and are not activated by each other. 

Biochem/physiol Actions

Methyl linolenate, a polyunsaturated fattly acid (PUFA), is used in studies on the mechanisms and prevention of oxidation/peroxidation of unsaturated fatty acids. Methyl linolenate is being studied as a possible skin whitening agent with anti-melanogenesis activity.

METHYL LINOLENATESupplier

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