Basic information Safety Supplier Related
ChemicalBook >  Product Catalog >  Chemical Reagents >  Organic reagents >  Imide >  (R)-(+)-1-Phenylethylamine

(R)-(+)-1-Phenylethylamine

Basic information Safety Supplier Related

(R)-(+)-1-Phenylethylamine Basic information

Product Name:
(R)-(+)-1-Phenylethylamine
Synonyms:
  • (1R)-1-PHENYLETHANAMINE
  • (1R)-1-PHENYLETHYLAMINE
  • (+)-D-ALPHA-METHYLBENZYLAMINE
  • D(+)-ALPHA-METHYLBENZYLAMINE
  • D-ALPHA-METHYLBENZYLAMINE
  • D-(+)-ALPHA-PHENYLETHYLAMINE
  • D-ALPHA-PHENYLETHYLAMINE
  • D-(+)-A-METHYLBENZYLAMINE
CAS:
3886-69-9
MF:
C8H11N
MW:
121.18
EINECS:
223-423-4
Product Categories:
  • Amines
  • Aromatics
  • chiral
  • Amines (Chiral)
  • Analytical Chemistry
  • Chiral Reagents
  • Asymmetric Synthesis
  • Chiral Building Blocks
  • e.e. / Absolute Configuration Determination (NMR)
  • Enantiomer Excess & Absolute Configuration Determination
  • for Resolution of Acids
  • Optical Resolution
  • Synthetic Organic Chemistry
  • Chiral Compound
  • Benzene derivatives
  • 3886-69-9
Mol File:
3886-69-9.mol
More
Less

(R)-(+)-1-Phenylethylamine Chemical Properties

Melting point:
-10 °C
alpha 
40 º (neat)
Boiling point:
187-189 °C(lit.)
Density 
0.952 g/mL at 20 °C(lit.)
vapor pressure 
0.5 mm Hg ( 20 °C)
refractive index 
n20/D 1.526(lit.)
Flash point:
175 °F
storage temp. 
2-8°C
solubility 
40g/l
form 
Liquid
pka
9.04±0.10(Predicted)
color 
Clear colorless
PH
>7 (40g/l, H2O, 20℃)
optical activity
[α]23/D +38°, neat
Water Solubility 
40 g/L (20 ºC)
Sensitive 
Air Sensitive
Merck 
14,6026
BRN 
2410916
InChIKey
RQEUFEKYXDPUSK-SSDOTTSWSA-N
LogP
1.31-1.49 at 25℃
CAS DataBase Reference
3886-69-9(CAS DataBase Reference)
NIST Chemistry Reference
Benzenemethanamine, «alpha»-methyl-, (R)-(3886-69-9)
EPA Substance Registry System
Benzenemethanamine, .alpha.-methyl-, (.alpha.R)- (3886-69-9)
More
Less

Safety Information

Hazard Codes 
C
Risk Statements 
21/22-34
Safety Statements 
26-28-36/37/39-45-28A-27
RIDADR 
UN 2735 8/PG 2
WGK Germany 
3
3-10-23-34
Autoignition Temperature
355 °C DIN 51794
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29214980

MSDS

More
Less

(R)-(+)-1-Phenylethylamine Usage And Synthesis

Chemical Properties

Colorless to light yellow liqui

Uses

(R)-(+)-1-Phenylethylamine is a chiral amine used for the determination of the enantiomeric purity of acids.

Uses

(R)-(+)-a-Methylbenzylamine also known as (R)-(+)-1-Phenylethylamine may be used in resolution of a chiral arylalkylamine involving high-conversion enantioselective condensation with capric acid followed by hydrolysis to yield corresponding (R)-(+)-amide.

Definition

ChEBI: The (R)-enantiomer of 1-phenylethanamine.

General Description

(R)-(+)-α-Methylbenzylamine is a chiral amine.

Flammability and Explosibility

Non flammable

Purification Methods

Dissolve the amine in toluene, dry over NaOH and distil; fraction boiling at 187-188o/atm is collected. Store it under N2 to avoid forming the carbamate and urea. Similarly for the S-(-) enantiomer [2627-86-3]. [Ingersoll Org Synth Coll Vol II 503 1943, Robinson & Snyder Org Synth Coll Vol III 717 1955, Beilstein 12 IV 2424, 2425.]

(R)-(+)-1-PhenylethylamineSupplier

Hubei Hicks Biochemical Co., Ltd Gold
Tel
17362916295; 17362916295
Email
w17362916295@163.com
Changsha Jing Kang New Material Technology Co., Ltd. Gold
Tel
0731-85118349 18874718518
Email
ma_haihong@sina.com
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. Gold
Tel
025-66099280 17798518460
Email
cfzhang@aikonchem.com
Shandong Vantage Specialty Chemicals Biotechnology Co., Ltd. Gold
Tel
133-96369453 18678026865
Email
sdfantai@163.com
Weifang Weimeng Chemical Co., Ltd. Gold
Tel
0536-8790166 15105445095
Email
weimengchem@163.com