Basic information Safety Supplier Related

TERPINYL FORMATE

Basic information Safety Supplier Related

TERPINYL FORMATE Basic information

Product Name:
TERPINYL FORMATE
Synonyms:
  • 3-Cyclohexene-1-methanol,.alpha.,.alpha.-4-trimethyl-,formate
  • alpha,alpha,4-trimethyl-3-cyclohexene-1-methanoformate
  • p-1-Menthen-8-ylformate
  • p-menth-1-en-8-ol,formate(mixedisomers)
  • p-menth-1-en-8-ylformate
  • TERPINYL FORMATE
  • TERPINYL FORMATE 97+% MIXTURE OF &
  • p-Menth-1-en-8-ylformiat
CAS:
2153-26-6
MF:
C11H18O2
MW:
182.26
EINECS:
218-444-0
Mol File:
2153-26-6.mol
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TERPINYL FORMATE Chemical Properties

Boiling point:
220 °C(lit.)
Density 
0.981 g/mL at 25 °C(lit.)
FEMA 
3052 | TERPINYL FORMATE
refractive index 
n20/D 1.471(lit.)
Flash point:
207 °F
color 
A colourless liquid.
Odor
at 100.00 %. floral lavender citrus fruity cypress herbal woody
Odor Type
floral
JECFA Number
367
LogP
3.26
EPA Substance Registry System
3-Cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl-, formate (2153-26-6)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
2
RTECS 
OT0220000
Toxicity
Both the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1976).

MSDS

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TERPINYL FORMATE Usage And Synthesis

Chemical Properties

Terpinyl formate has a pleasant, floral, citrus odor with a bitter taste at high levels, becoming dry and fruity at lower levels.

Occurrence

Reported present in Ceylon cardamom essential oil.

Uses

Terpinyl formate finds some use in Citrus-colognes, in support of Neroli notes, Lavender-Bergamot-notes, green notes, etc. It is also used in certain topnote compositions with Citrus oils and "green" materials.

Preparation

By cold formylation of terpineol, using formic-acetic anhydride (Arctander, 1969). Uses: In public use before the 1920s. Use in fragrances in the USA amounts to approximately 10001b/yr.

Definition

ChEBI: Alpha-Terpineol formate is a p-menthane monoterpenoid.

Synthesis

May be produced from d-α-terpineol and formic acetic anhydride; the racemic α-terpineol is also obtained by an analogous synthesis.

TERPINYL FORMATESupplier

Sigma-Aldrich
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