6-CYANOHEXYLZINC BROMIDE
6-CYANOHEXYLZINC BROMIDE Basic information
- Product Name:
- 6-CYANOHEXYLZINC BROMIDE
- Synonyms:
-
- 6-CYANOHEXYLZINC BROMIDE, 0.5M SOLUTIONI N TETRAHYDROFURAN
- 6-CYANOHEXYLZINC BROMIDE
- 6-Cyanohexylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
- 6-cyanohexylzinc bromide solution
- 6-Cyanohexylzinc bromide solution 0.5 in THF
- 6-Cyanohexylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles
- 6-Cyanohexylzinc bromide solution 0.5M in THF
- 6-Cyanohexylzinc bromide 0.5 M in Tetrahydrofuran
- CAS:
- 312624-28-5
- MF:
- C7H12BrNZn
- MW:
- 255.47
- Product Categories:
-
- Alkyl
- Organozinc Halides
- Reike and Organozinc Reagents
- Mol File:
- 312624-28-5.mol
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6-CYANOHEXYLZINC BROMIDE Chemical Properties
- Density
- 0.944 g/mL at 25 °C
- Flash point:
- 1 °F
- storage temp.
- 2-8°C
- Sensitive
- Air Sensitive
- Exposure limits
- ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
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Safety Information
- Hazard Codes
- F,Xn
- Risk Statements
- 19-22-36/38-40-36/37-14-11
- Safety Statements
- 16-26-33-36-36/37
- RIDADR
- UN 2056 3/PG 2
- WGK Germany
- 1
- HazardClass
- 4.3
MSDS
- Language:English Provider:SigmaAldrich
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6-CYANOHEXYLZINC BROMIDE Usage And Synthesis
Uses
6-Cyanohexylzinc bromide is an organozinc compound, which can be used as a reactant in palladium-catalyzed Negishi cross-coupling reaction to construct carbon-carbon bonds by coupling with organic halides or triflates.
It can also be used as a reactant to synthesize:
- Cyanohexyl substituted aryl derivatives by palladium catalyzed coupling reaction with aryl bromides.
- Methyl 5-(6-cyanohexyl)-3-methylfuran-2-carboxylate, a key intermediate which is used in the preparation of cyclic furfuryl ether via Wittig rearrangement.
6-CYANOHEXYLZINC BROMIDESupplier
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Sigma-Aldrich
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