1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE Chemical Properties

Melting point:

168-173 °C (lit.)

Boiling point:

299.7±9.0 °C(Predicted)

Density 

1.064±0.06 g/cm3(Predicted)

storage temp. 

Sealed in dry,Room Temperature

BRN 

1913257

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

WGK Germany 

3

MSDS

• Language:English Provider:SigmaAldrich

1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE Usage And Synthesis

Uses

1-Bromo-2,4,6-tri-tert-butylbenzene was used in the synthesis of bulky biarylphosphine ligand. This ligand was reported to participate in the Pd-catalyzed C-O cross-coupling of a wide range of aryl halides and phenols under milder conditions. It was used to investigate the effect on oligomerization of increased steric bulk in dimethylindium(III) chalcogenolates. It may be used to form α,α-dimethyl-β-phenyl hydrostyrene by reacting with phenylboronic acid.

General Description

1-Bromo-2,4,6-tri-tert-butylbenzene (2,4,6-tri-tert-butylbromobenzene) is a hindered aryl bromide. 1-Bromo-2,4,6-tri-tert-butylbenzene on reaction with phenylboronic acid yields α,α-dimethyl-β-phenyl hydrostyrene.

1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE(3975-77-7)Related Product Information

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