2-Thienylmagnesium bromide solution Chemical Properties

Boiling point:

65 °C

Density 

1.011 g/mL at 25 °C

Flash point:

−6 °F

form 

Solution

color 

Yellow to orange to brown

Safety Information

Hazard Codes 

F,C,Xn

Risk Statements 

11-14-19-22-34-40-36/37

Safety Statements 

16-26-36/37/39-45-36/37

RIDADR 

UN 2924 3/PG 2

WGK Germany 

1

HS Code 

29349990

2-Thienylmagnesium bromide solution Usage And Synthesis

Chemical Properties

Yellow to orange to brown liquid

Uses

2-Thienylmagnesium bromide is a Grignard reagent that can be used as a reactant to synthesize:

• 1-(2-thienyl)-carbinols by condensation reaction with aldehydes. Carbinols are further dehydrated to form 2-thienyl olefins.
• Thiophene-functionalized polystyrene macromonomer (ThPStM), which is employed as a key intermediate to synthesize polystyrene-graft-polythiophene (PSt-g-PTh) via a combination of atom transfer radical polymerization (ATRP) and Grignard reaction.
• Thienylene oligomers, which are used as conducting polymers and as potential OLEDs.

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