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Bis(4-tert-butylcyclohexyl) peroxydicarbonate

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Bis(4-tert-butylcyclohexyl) peroxydicarbonate Basic information

Product Name:
Bis(4-tert-butylcyclohexyl) peroxydicarbonate
Synonyms:
  • Bis(5-tert-butylcyclohexyl) peroxydicarbonate
  • 1-tert-butyl-1-[(1-tert-butylcyclohexyl)-methyldioxymethyl]cyclohexane
  • 4-TERT-BUTYLCYCLOHEXYL {[(4-TERT-BUTYLCYCLOHEXYL)OXY]CARBONYL}OXY CARBONATE
  • Di-(4-tert.-butylcyclohexyl)-peroxydicarbonat
  • Bis(4-tert-butylcyclohexyl) peroxydicarbonate
  • Di-(4-tert-butylcyclohexyl)peroxydicarbonate
  • Perkadox 16
  • Perkadox
CAS:
15520-11-3
MF:
C22H38O6
MW:
398.53
EINECS:
239-557-1
Mol File:
15520-11-3.mol
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Bis(4-tert-butylcyclohexyl) peroxydicarbonate Chemical Properties

Melting point:
91-92°C
Boiling point:
435.1±28.0 °C(Predicted)
Density 
1.06±0.1 g/cm3(Predicted)
vapor pressure 
0.01Pa at 20℃
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Solid
color 
White to Off-White
Water Solubility 
600ng/L at 20℃
Stability:
Light Sensitive
LogP
8.34
EPA Substance Registry System
Peroxydicarbonic acid, C,C'-bis[4-(1,1-dimethylethyl)cyclohexyl] ester (15520-11-3)
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Safety Information

Hazard Codes 
O
Risk Statements 
7
Safety Statements 
3-7-14-36/37/39-17
RIDADR 
UN 3114 5.2
WGK Germany 
1
HS Code 
29209090

MSDS

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Bis(4-tert-butylcyclohexyl) peroxydicarbonate Usage And Synthesis

Chemical Properties

Colorless solid

Chemical Properties

Bis(4-tert-butylcyclohexyl) peroxydicarbonate is crystalline solid (white powder) with slight odor, sensitive to heat and contamination, and may decompose violently or explosively at temperature 0–10°C, owing to self-accelerating exothermic decomposition due to shock, heat, or friction. To lessen the explosion risk, di-(4-tert-butylcyclohexyl) peroxydicarbonate should be stored in a temperature controlled vessel and mixed with water to form a slurry of the peroxide. Hazardous polymerization does not occur (12c). Detached storage is preferred for this chemical, including out of direct sunlight in a cool wellventilated place. It should be stored away from combustibles and other incompatible materials, including strong acids, bases, oxidizers, reducing agents, amines, and promoters/ accelerators, which may result in a violent decomposition or explosion. Refer to the Code for the Storage of Organic Peroxide Formulations (13a).

Uses

Bis(4-(tert-butyl)cyclohexyl) Peroxydicarbonate is a useful raw material used in the preparation of polymerizable yellow azo dyes applied in artificial intraocular lens. A catalyst.

Uses

Di-(4-tert-butylcyclohexyl) peroxy dicarbonate is used as polymerization initiator. No information was located for this compound.

General Description

Crystalline solid. Bis(4-tert-butylcyclohexyl) peroxydicarbonate is particularly heat and contamination sensitive. These materials above a given "control temperature" may decompose violently. They are often stored in a temperature controlled vessel, also mixed with water to form a slurry of the peroxide. This greatly lessens the explosion hazard risk.

Reactivity Profile

DI-(4-TERT-BUTYLCYCLOHEXYL)PEROXYDICARBONATE decomposes violently or explosively at temperatures 0-10° C. owing to self-accelerating exothermic decomposition; Several explosions were due to shock, heat or friction; amines and certain metals can cause accelerated decomposition [Bretherick, 1979 p. 156].

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