Palladium, [butylbis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine](methanesulfonato-κO)[2'-(methylamino-κN)[1,1'-biphenyl]-2-yl-κC]-
Palladium, [butylbis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine](methanesulfonato-κO)[2'-(methylamino-κN)[1,1'-biphenyl]-2-yl-κC]- Basic information
- Product Name:
- Palladium, [butylbis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine](methanesulfonato-κO)[2'-(methylamino-κN)[1,1'-biphenyl]-2-yl-κC]-
- Synonyms:
-
- Palladium, [butylbis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine](methanesulfonato-κO)[2'-(methylamino-κN)[1,1'-biphenyl]-2-yl-κC]-
- Methanesulfonato[(di(1-adamantyl)-n-butylphos-phine)-2-(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
- cataCXium A Pd G4
- Formed catalyst cataCXium? A Pd G4
- Methanesulfonato[(di(1-adamantyl)-n-butylphos-phine)](2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) (cataCXium Pd G4)
- Mesylate[(di(1-adamantyl)-n-butylphosphine)-2-(2'-MeNH-1,1'-biphenyl)]palladium(II)
- Methanesulfonato[(di(1-adamantyl)-n-butylphos-phine)-2-(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II),cataCXium Pd G4
- bis(1-adamantyl)-butyl-phosphane (N-methyl-2-phenyl-anilino)-methylsulfonyloxy-palladium
- CAS:
- 2230788-67-5
- MF:
- C38H54NO3PPdS
- MW:
- 742.31
- Mol File:
- 2230788-67-5.mol
More
Less
Palladium, [butylbis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine](methanesulfonato-κO)[2'-(methylamino-κN)[1,1'-biphenyl]-2-yl-κC]- Chemical Properties
- storage temp.
- 2-8°C, protect from light
- form
- solid
- Appearance
- Off-white to gray Solid
- InChIKey
- FOIUZOZBEHPFHG-UHFFFAOYSA-N
- SMILES
- P(C12CC3CC(CC(C3)C1)C2)(C12CC3CC(CC(C3)C1)C2)([Pd+2]1(N(C2=CC=CC=C2C2=CC=CC=[C-]12)C)[O-]S(=O)(=O)C)CCCC
More
Less
Palladium, [butylbis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine](methanesulfonato-κO)[2'-(methylamino-κN)[1,1'-biphenyl]-2-yl-κC]- Usage And Synthesis
Uses
A fourth generation (G4) Buchwald precatalyst that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations found when using the third generation precatalysts. It is air, moisture, and thermally-stable and shows good solubility in common organic solvents.
reaction suitability
reagent type: catalyst
core: palladium
reaction type: Cross Couplings
Palladium, [butylbis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine](methanesulfonato-κO)[2'-(methylamino-κN)[1,1'-biphenyl]-2-yl-κC]-Supplier
BeiJing Greenchem Technology Co.,Ltd. Gold
- Tel
- 131-21959385 18804271668
- chemrocking@bjgreenchem.com
Beijing HwrkChemical Technology Co., Ltd
- Tel
- 18515581800 18501085097
- sales.bj@hwrkchemical.com
Beijing Ouhe Technology Co., Ltd
- Tel
- 010-010-82967028 13522913783
- 2355560935@qq.com
WuHan Taiyukaishang Chemical Co., Ltd.
- Tel
- 027-027-87680032 18963957250
- taiyuchem@163.com
Bide Pharmatech Ltd.
- Tel
- 400-164-7117 13681763483
- product02@bidepharm.com