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Sennoside A

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Sennoside A Basic information

Product Name:
Sennoside A
Synonyms:
  • Sennoside A std.
  • SENNOSIDEA60%
  • SENNOSIDE A(P)
  • SENNOSIDE A(SH)
  • SENNOSIDA
  • CALCIUM SENNOSIDE 5%, 10%, 20%, 60%
  • [9,9'-Bianthracene]-2,2'-dicarboxylicacid,5,5'-bis(β-D-glucopyranosyloxy)-9,9',10,10'-tetrahydro-4,4'-dihydroxy-10,10'-dioxo-,(9R,9'R)-
  • Sennoside A1
CAS:
81-27-6
MF:
C42H38O20
MW:
862.74
EINECS:
201-339-9
Product Categories:
  • The group of Sennosides
  • Anthraquinones, Hydroquinones and Quinones
  • chemical reagent
  • pharmaceutical intermediate
  • phytochemical
  • reference standards from Chinese medicinal herbs (TCM).
  • standardized herbal extract
  • Inhibitors
Mol File:
81-27-6.mol
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Sennoside A Chemical Properties

Melting point:
>191oC (dec.)
alpha 
D20 -164° (c = 0.1 in 60% acetone); D20 -147° (c = 0.1 in 70% acetone); D20 -24° (c = 0.2 in 70% dioxane)
Boiling point:
1144.8±65.0 °C(Predicted)
Density 
1.743±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Aqueous Base (Slightly, Heated), DMSO (Slightly, Heated)
form 
Solid
pka
3.31±0.40(Predicted)
color 
Yellow to Dark Yellow
BRN 
5723746
Stability:
Hygroscopic
InChIKey
IPQVTOJGNYVQEO-KGFNBKMBSA-N
LogP
1.880 (est)
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Safety Information

Risk Statements 
22
Safety Statements 
22-45
WGK Germany 
3
3-10
HS Code 
29173990

MSDS

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Sennoside A Usage And Synthesis

Chemical Properties

Light yellow powder

Uses

a natural anthroquinonone glucoside calcium complex with laxative properties

Uses

Sennoside A is used as a laxative in the treatment of constipation. In addition. it is hypothesized to induce cell proliferation and may be a potential carcinogenic agent.

Definition

ChEBI: Sennoside A is a member of the class of sennosides that is rel-(9R,9'R)-9,9',10,10'-tetrahydro-9,9'-bianthracene-2,2'-dicarboxylic acid which is substituted by hydroxy groups at positions 4 and 4', by beta-D-glucopyranosyloxy groups at positions 5 and 5', and by oxo groups at positions 10 and 10'. The exact stereochemisty at positions 9 and 9' is not known - it may be R,R (as shown) or S,S. It is a member of sennosides and an oxo dicarboxylic acid.

Purification Methods

Sennoside A (bianthraquinonyl-bis-glucoside R,R-enantiomer) [81-27-6] M 862.7, m 220 -2 4 0o(dec), [ ] D -164o (c 0.1, Me2CO/H2O 6:4), [ ] D -24o (c 0.2, 70% aqueous dioxane). Sennoside A forms yellow crystals from aqueous acetone, 2-ethoxyethanol or large volumes of H2O. [Stoll et al. Helv Chim Acta 32 1896 1900, Beilstein 17 III/IV 3403.]

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