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Iridium trichloride

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Iridium trichloride Basic information

Product Name:
Iridium trichloride
Synonyms:
  • iridiumchloride(ircl3)
  • IRIDIUM(+3)CHLORIDE
  • IRIDIUM CHLORIDE
  • IRIDIUM(III) CHLORIDE
  • IRIDIUM TRICHLORIDE
  • IRIDIUM(III) CHLORIDE, CRYSTALS
  • Iridium(III) chloride, 99.9+% metals basis
  • Iridium(III) chloride anhydrous
CAS:
10025-83-9
MF:
Cl3Ir
MW:
298.58
EINECS:
233-044-6
Product Categories:
  • chemical reaction,pharm,electronic,materials
  • metal halide
  • Inorganics
  • Iridium Salts
  • Metal and Ceramic Science
  • Salts
  • Crystal Grade Inorganics
  • IridiumMetal and Ceramic Science
Mol File:
10025-83-9.mol
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Iridium trichloride Chemical Properties

Melting point:
763 °C(lit.)
Density 
5,3 g/cm3
storage temp. 
Inert atmosphere,Room Temperature
solubility 
H2O: insoluble(lit.)
form 
Powder
Specific Gravity
5.3
color 
Green to brown
Water Solubility 
insoluble
Sensitive 
Hygroscopic
Crystal Structure
AlCl3 type
crystal system
Monoclinic
Merck 
14,5088
Space group
C2/m
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.5991.0370.59990109.4900.351
Stability:
Stable. Protect from moisture.
Major Application
PEM fuel cells
homogeneous catalyst
material synthesis precursor
InChI
1S/3ClH.Ir/h3*1H;/q;;;+3/p-3
InChIKey
DANYXEHCMQHDNX-UHFFFAOYSA-K
SMILES
Cl[Ir](Cl)Cl
CAS DataBase Reference
10025-83-9(CAS DataBase Reference)
EPA Substance Registry System
Iridium chloride (IrCl3) (10025-83-9)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
1759
WGK Germany 
3
TSCA 
TSCA listed
HazardClass 
8
HS Code 
2827398590
Storage Class
11 - Combustible Solids
Hazard Classifications
Eye Irrit. 2

MSDS

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Iridium trichloride Usage And Synthesis

Chemical Properties

brown powder

Uses

Iridium(III) chloride is used in iridium electroplating, in making the standard meter bar of paris and crucibles. It is used for high temperature electrical contacts, as hardening agent, in tipping pens and compass bearings and Pt/Ir spark plugs. It is used for medical, surgical or other patient oriented applications, MMO (mixed metal oxide) titanium electrode coatings and as a starting material for heterogeneous catalysts.

Synthesis

Iridium to hexachloro iridium (IV) acid ammonium (NH4) 2 [IrCl6] form from the platinum system elements, it is reduced by the hydrogen stream, to get the spongy metal iridium, which then reacts with chlorine at 300-400 ?? C to produce iridium trichloride. It has the same AlCl3 structure as rhodium trichloride.

By co-heating hydrated iridium(III) oxide with hydrochloric acid, a hydrate of iridium trichloride can be crystallized.

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