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potassium trifluoromethanesulfonate

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potassium trifluoromethanesulfonate Basic information

Product Name:
potassium trifluoromethanesulfonate
Synonyms:
  • POTASSIUM TRIFLATE
  • POTASSIUM TRIFLUOROMETHANESULFONIC ACID
  • POTASSIUM TRIFLUOROMETHANESULPHONATE
  • TRIFLUOROMETHANESULFONIC ACID POTASSIUM SALT
  • TRIFLUOROMETHANESULFINIC ACID, POTASSIUM SALT
  • POTASSIUM TRIFLUOROMETHANESULFINATE
  • potassium trifluoromethanesulphinate
  • Trifluoromethane sulphinic acid potassium salt
CAS:
41804-89-1
MF:
CF3O2S.K
MW:
172.17
EINECS:
255-556-9
Mol File:
41804-89-1.mol
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potassium trifluoromethanesulfonate Chemical Properties

Melting point:
236-241 °C
Stability:
Stable. Incompatible with astrong oxidizing agents. Protect from moisture. Hygroscopic.
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38-38-37-36
Safety Statements 
26-36
WGK Germany 
3
3-10
HS Code 
2930200090

MSDS

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potassium trifluoromethanesulfonate Usage And Synthesis

Chemical Properties

white powder

Uses

Potassium Trifluoromethanesulfinate is used in preparation of trifluoromethanesulfonyl compounds.

Application

Potassium trifluoromethanesulfonate is used as a reagent in the synthesis of guanine-quadruplex hybrid materials. 

Synthesis

At first, an aqueous solution was prepared by dissolving 125 g of potassium sulfite in 290 g of water. Then, a metal pressure-proof reactor was charged with this aqueous solution. Then, the atmosphere of the reactor was removed to obtain a reduced pressure. After that, 30.7 g of trifluoromethanesulfonic fluoride was added to the reactor, stirring from 0° C. to room temperature for 12 hr. The resulting reaction liquid was neutralized with potassium carbonate, followed by water removal. Then, methanol was added to the remaining solid matter to extract the target product. The resulting methanol solution was concentrated to dryness, obtaining 32.6 g of potassium trifluoromethanesulfonate (94%).

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