Basic information Safety Supplier Related

4-(2,4-DINITROANILINO)PHENOL

Basic information Safety Supplier Related

4-(2,4-DINITROANILINO)PHENOL Basic information

Product Name:
4-(2,4-DINITROANILINO)PHENOL
Synonyms:
  • acetoquinonelightyellow2rz
  • Amacel Yellow RR
  • amacelyellowrr
  • C.I. 10345
  • C.I. Disperse Yellow 1
  • C.I. Solvent yellow 52
  • c.i.10345
  • c.i.disperseyellow1
CAS:
119-15-3
MF:
C12H9N3O5
MW:
275.22
EINECS:
204-300-4
Mol File:
119-15-3.mol
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4-(2,4-DINITROANILINO)PHENOL Chemical Properties

Melting point:
191 °C (dec.)(lit.)
Boiling point:
418.17°C (rough estimate)
Density 
1.3877 (rough estimate)
refractive index 
1.5700 (estimate)
solubility 
Chloroform (Very Slightly), DMSO (Slightly)
form 
Solid
pka
10.20±0.26(Predicted)
color 
Very Dark Orange
Water Solubility 
2.477mg/L(25 ºC)
CAS DataBase Reference
119-15-3(CAS DataBase Reference)
EPA Substance Registry System
4-(2,4-Dinitroanilino)phenol (119-15-3)
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Safety Information

Hazard Codes 
F,Xi
Risk Statements 
11-36/37/38
Safety Statements 
16-26-33-36/37/39
RIDADR 
UN 1325 4.1/PG 2
WGK Germany 
2
RTECS 
SL3070000
HazardClass 
4.1
PackingGroup 
III

MSDS

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4-(2,4-DINITROANILINO)PHENOL Usage And Synthesis

Uses

Disperse Yellow 1 is an azo disperse dye which is water insoluble. Disperse Yellow 1 can be used to dye polyester and acetate fibers. Dyes and metabolites, Environmental Testing.

Preparation

4-Aminophenol and 1-Chloro-2,4-dinitrobenzene??condensation

General Description

Reddish-brown solid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4-(2,4-DINITROANILINO)PHENOL is an organonitrate/phenol. Organonitrate compounds range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups. Phenols do not behave as organic alcohols, as one might guess from the presence of a hydroxyl (-OH) group in their structure. Instead, they react as weak organic acids. Phenols and cresols are much weaker as acids than common carboxylic acids (phenol has Ka = 1.3 x 10^[-10]). These materials are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction between phenols and bases.

Fire Hazard

Flash point data for 4-(2,4-DINITROANILINO)PHENOL are not available, however, 4-(2,4-DINITROANILINO)PHENOL is probably combustible.

Properties and Applications

yellow. Insoluble in water, slightly soluble in alcohol. In concentrated sulfuric acid for claybank, dilution after yellow. Used for cellulose ester, polystyrene and other thermoplastic resin paint color.

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