PHENACYLTRIPHENYLPHOSPHONIUM BROMIDE Chemical Properties

Melting point:

265-268 °C (dec.) (lit.)

storage temp. 

Inert atmosphere,Room Temperature

solubility 

very faint turbidity in Methanol

form 

solid

color 

White to Light yellow to Light orange

Sensitive 

Hygroscopic

BRN 

3642554

InChI

1S/C26H22OP.BrH/c27-26(22-13-5-1-6-14-22)21-28(23-15-7-2-8-16-23,24-17-9-3-10-18-24)25-19-11-4-12-20-25;/h1-20H,21H2;1H/q+1;/p-1

InChIKey

AEHDSYHVTDJGDN-UHFFFAOYSA-M

SMILES

[Br-].O=C(C[P+](c1ccccc1)(c2ccccc2)c3ccccc3)c4ccccc4

CAS DataBase Reference

6048-29-9(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-37/39

WGK Germany 

3

RTECS 

TA2400000

HS Code 

29310099

Storage Class

11 - Combustible Solids

Hazard Classifications

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

PHENACYLTRIPHENYLPHOSPHONIUM BROMIDE Usage And Synthesis

Chemical Properties

LIGHT BEIGE AMORPHOUS POWDER

Uses

Catalyst for protections and deprotection of alcohols via etherification

Reactant involved in:

• Investigations of gas-phase pyrolysis
• Asymmetric hydroxylamine / enone cascade reactions
• Reductive Michael cyclizations
• Microwave-assisted Wittig olefination
• Synthesis of polyfunctionally substituted heterocycles

reaction suitability

reaction type: C-C Bond Formation

PHENACYLTRIPHENYLPHOSPHONIUM BROMIDE(6048-29-9)Related Product Information

• Methyltriphenylphosphonium bromide
• Triphenyl(propyl)phosphonium bromide
• ACETONYL TRIPHENYLPHOSPHONIUM BROMIDE
• (ALPHA-METHYLPHENACYL)TRIPHENYLPHOSPHONIUM BROMIDE
• Ethyltriphenylphosphonium bromide
• AURORA KA-1150
• DIPHENYL-N-PROPYLPHOSPHINE
• PHENACYLTRIPHENYLPHOSPHONIUM BROMIDE