ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Siloxane > 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Basic information
- Product Name:
- 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
- Synonyms:
-
- 1-(Trimethylsilyloxy)-1-phenylethene
- 1-Phenyl-1-trimethylsiloxyethene
- 1-Phenylvinyl trimethylsilyl ether
- (1-Phenylethenyloxy)trimethylsilane
- [(1-Phenylethenyl)oxy]trimethylsilane
- à-(trimethylsiloxy)styrene
- α-(trimethylsiloxy)styrene
- 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE 97%
- CAS:
- 13735-81-4
- MF:
- C11H16OSi
- MW:
- 192.33
- EINECS:
- 237-308-1
- Product Categories:
-
- Building Blocks
- Chemical Synthesis
- Monoalkoxysilanes
- Enol Ethers
- Organic Building Blocks
- Oxygen Compounds
- Si (Classes of Silicon Compounds)
- Silicon Compounds (for Synthesis)
- Si-O Compounds
- Synthetic Organic Chemistry
- Mol File:
- 13735-81-4.mol
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1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Chemical Properties
- Melting point:
- 122-123 °C
- Boiling point:
- 88-89 °C/11 mmHg (lit.)
- Density
- 0.938 g/mL at 25 °C (lit.)
- vapor density
- >1 (vs air)
- refractive index
- n20/D 1.502(lit.)
- Flash point:
- 174 °F
- storage temp.
- 2-8°C
- form
- clear liquid
- color
- Colorless to Light orange to Yellow
- Specific Gravity
- 0.938
- Water Solubility
- Reacts with water.
- Sensitive
- Moisture Sensitive
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- BRN
- 1306914
- CAS DataBase Reference
- 13735-81-4(CAS DataBase Reference)
- EPA Substance Registry System
- Silane, trimethyl[(1-phenylethenyl)oxy]- (13735-81-4)
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MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
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1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Usage And Synthesis
Uses
1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of β-amino ketones in water via Mannich-type reaction and cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction. It is also used as chemical additives and intermediates.
Uses
1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of:
- β-amino ketones in water via Mannich-type reaction
- cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction
General Description
1-Phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran. It also undergoes Mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants.
1-PHENYL-1-TRIMETHYLSILOXYETHYLENESupplier
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