ISOPROPYLDIPHENYLPHOSPHINE Chemical Properties

Melting point:

40-43 °C (lit.)

Boiling point:

165 °C/11 mmHg (lit.)

Density 

0.861

Flash point:

>230 °F

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

form 

solid

color 

White or Colorless to Almost white or Almost colorless

Sensitive 

Air Sensitive

InChI

InChI=1S/C15H17P/c1-13(2)16(14-9-5-3-6-10-14)15-11-7-4-8-12-15/h3-13H,1-2H3

InChIKey

LLZAIAIZAVMQIG-UHFFFAOYSA-N

SMILES

P(C(C)C)(C1=CC=CC=C1)C1=CC=CC=C1

CAS DataBase Reference

6372-40-3(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-37/39

WGK Germany 

3

HS Code 

2931.90.6000

MSDS

• Language:English Provider:SigmaAldrich

ISOPROPYLDIPHENYLPHOSPHINE Usage And Synthesis

Uses

Catalyst in:

• Nickel/Lewis acid-catalyzed aryl- and alkenylcyanation of unsaturated bonds
• Nickel/Lewis Acid-Catalyzed Cyanoesterification and Cyanocarbamoylation of Alkynes
• Methoxycarbonylation reactions (palladium complex)
• Decarboxylative cross-coupling in the presence of palladium
• Asymmetric hydrogenation of quinolines catalyzed by iridium complexes of BINOL-derived diphosphonites
• Hydroesterification of vinylarenes in complex with palladium

• Ligand precatalyst for room-temperature Heck coupling reactions

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

ISOPROPYLDIPHENYLPHOSPHINE(6372-40-3)Related Product Information

• Isopropylsulfonamide
• ISOPROPYLHYDRAZINE HYDROCHLORIDE
• (2S,4S)-4-Diphenylphosphino 2-diphenylphosphinomethyl pyrrolidine
• [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
• R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE
• (S)-(+)-NEOMENTHYLDIPHENYLPHOSPHINE
• Cyclohexyldiphenylphosphine
• ISOPROPYLTRIPHENYLPHOSPHONIUM IODIDE
• ISOPROPYLDIPHENYLPHOSPHINE
• (2-BUTYL)TRIPHENYLPHOSPHONIUM BROMIDE
• (9-FLUORENYL)TRIPHENYLPHOSPHONIUM BROMIDE
• 1,1'-Bis(diphenylphosphino)ferrocene
• CYCLOHEXYLDIPHENYLPHOSPHINE OXIDE
• CYCLOPROPYLTRIPHENYLPHOSPHONIUM BROMIDE
• (2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE
• [1-(Ethoxycarbonyl)ethyl]triphenylphosphonium bromide
• CYCLOHEXYLTRIPHENYLPHOSPHONIUM BROMIDE
• ISOPROPYLDIPHENYLPHOSPHINE OXIDE, 97