TERT-BUTYLDIPHENYLPHOSPHINE Chemical Properties

Melting point:

52-55 °C(lit.)

Boiling point:

144-146 °C2 mm Hg(lit.)

Flash point:

>230 °F

storage temp. 

Inert atmosphere,Room Temperature

form 

crystal

color 

white

InChIKey

QZUPHAGRBBOLTB-UHFFFAOYSA-N

Safety Information

Risk Statements 

22-36/37/38

Safety Statements 

26-37

WGK Germany 

3

TSCA 

No

MSDS

• Language:English Provider:SigmaAldrich

TERT-BUTYLDIPHENYLPHOSPHINE Usage And Synthesis

Uses

New family of Ph2(t-Bu)P phosphines for efficient Silyl-Heck transformations.

Uses

Catalyst for:

• Nickel/Lewis acid-catalyzed carbocyanation of alkynes with acetonitrile or substituted acetonitriles
• Palladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditions
• Palladium to form a catalyst for methoxycarbonylation reactions
• Ru-catalyzed transfer hydrogenation in reductive coupling of disubstituted allenes with aldehydes
• Stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes

• Phosphine ligand in nickel-catalyzed carbocyanation of alkynes
• Monodentate P-Donor Ligands (LKB-P)

Definition

ChEBI: NSC 244302 is a member of benzenes.

TERT-BUTYLDIPHENYLPHOSPHINE(6002-34-2)Related Product Information

• tert-Butylchlorodiphenylsilane
• tert-Butyldimethylsilyl chloride
• Tert-butyldicyclohexylphosphine tetrafluoroborate
• tert-Butyl methyl ether
• Dicyclohexyl(2-Methylphenyl)phosphine
• Cyclohexyldiphenylphosphine
• T-BUTYLDICYCLOHEXYLPHOSPHINE
• DI-TERT-BUTYLPHENYLPHOSPHINE
• ETHYLDIPHENYLPHOSPHINE
• DIPHENYL-N-PROPYLPHOSPHINE
• METHYLDIPHENYLPHOSPHINE
• DI-T-BUTYLCYCLOHEXYLPHOSPHINE
• DIPHENYL(P-TOLYL)PHOSPHINE
• 1-CARBETHOXYCYCLOPROPYLTRIPHENYLPHOSPHONIUM TETRAFLUOROBORATE
• TRIPHENYLMETHYL TRIPHENYLPHOSPHONIUM CHLORIDE
• T-BUTYLPHOSPHINE
• ISOPROPYLDIPHENYLPHOSPHINE
• TERT-BUTYLDIPHENYLPHOSPHINE