Phenylselenenyl chloride
Phenylselenenyl chloride Basic information
- Product Name:
- Phenylselenenyl chloride
- Synonyms:
-
- PHENYLSELENENYL CHLORIDE
- PHENYLSELENIUM CHLORIDE
- PHENYLSELENYL CHLORIDE
- chloroselenobenzene
- Phenylselenenylchloride,98%
- Phenylselenyl chloride, 97+%
- Benzeneselenenyl chloride, Benzeneselenyl chloride
- Phenylselenyl chloride, 98% 10GR
- CAS:
- 5707-04-0
- MF:
- C6H5ClSe
- MW:
- 191.52
- EINECS:
- 227-196-2
- Product Categories:
-
- Classes of Metal Compounds
- Se (Selenium) Compounds
- Semimetal Compounds
- organoselenides
- Mol File:
- 5707-04-0.mol
Phenylselenenyl chloride Chemical Properties
- Melting point:
- 59-62 °C (lit.)
- Boiling point:
- 120 °C/20 mmHg (lit.)
- Flash point:
- 120°C/20mm
- storage temp.
- Store below +30°C.
- solubility
- Soluble in methanol.
- form
- crystal
- color
- red
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- Sensitive
- Moisture Sensitive
- BRN
- 1237091
- Exposure limits
- ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3 - Stability:
- Stable, but may be air or moisture sensitive. Incompatible with strong bases, strong oxidizing agents.
- InChI
- InChI=1S/C6H5ClSe/c7-8-6-4-2-1-3-5-6/h1-5H
- InChIKey
- WJCXADMLESSGRI-UHFFFAOYSA-N
- SMILES
- C1([Se]Cl)=CC=CC=C1
- CAS DataBase Reference
- 5707-04-0(CAS DataBase Reference)
Safety Information
- Hazard Codes
- T,N
- Risk Statements
- 23/25-33-50/53
- Safety Statements
- 20/21-28-45-60-61
- RIDADR
- UN 2928 6.1/PG 2
- WGK Germany
- 3
- F
- 10-21
- TSCA
- No
- HazardClass
- 6.1
- PackingGroup
- II
- HS Code
- 29319090
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
Phenylselenenyl chloride Usage And Synthesis
Chemical Properties
crystalline solid
Uses
Phenylselenenyl chloride is used in the preparation of (cyclobut-1-enylselanyl)benzene. It is an important versatile reagent used in organic synthesis. Further, it serves as a useful synthon for 2-amino alcohols.
Application
Phenylselenenyl chloride as a reagent for the facile preparation of cyclic ethers from diolefins[1].
General Description
Phenylselenyl chloride is a synthon for 2-amino alcohols. It is a versatile reagent in organic synthesis.
Purification Methods
Purify it by distillation in a vacuum, and recrystallisation (orange needles) from hexane [Foster J Am Chem Soc 55 822 1933, Foster et al. Recl Trav Chim, Pays-Bas 53 405, 408 1934, Behaghel & Seibert Chem Ber 66 714 1933]. [Beilstein 6 III 1110.] HIGHLY TOXIC.
References
[1] S. Uemura. “Phenylselenenyl chloride as a reagent for the facile preparation of cyclic ethers from diolefins.” Tetrahedron Letters 21 1 (1980): 1533–1536.
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Phenylselenenyl chloride(5707-04-0)Related Product Information
- Selenium sulfide
- SELENIUM CHLORIDE
- PHENYLSELENOL
- DIETHYLDISELENIDE
- Selenium Oxychloride
- Selenium
- Phenylsilane
- Diphenyl diselenide
- Selenium tetrachloride
- DIPHENYL SELENIDE
- Selenium dioxide
- Selenic acid
- DIMETHYLSELENIDE
- Phenyltris(trimethylsiloxy)silane
- Phenyltriethoxysilane
- Trimethoxyphenylsilane
- PHENYLTHIOACETONITRILE
- Phenyltrichlorosilane