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1,3-Dimethyluracil

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1,3-Dimethyluracil Basic information

Product Name:
1,3-Dimethyluracil
Synonyms:
  • TIMTEC-BB SBB004164
  • 3h)-pyrimidinedione,1,3-dimethyl-4(1h
  • N,N'-Dimethyluracil
  • N1,N3-Dimethyluracil
  • Uracil, 1,3-dimethyl-
  • 1,3-dimethyl-2,4-pyrimidinedione
  • N-methyl-4-[(2-methyl-1,2,4-triazol-3-yl)azo]-N-(phenylmethyl)aniline
  • 1,3-dimethylpyrimidine-2,4-dione
CAS:
874-14-6
MF:
C6H8N2O2
MW:
140.14
EINECS:
212-856-4
Product Categories:
  • Pyridines, Pyrimidines, Purines and Pteredines
  • bc0001
Mol File:
874-14-6.mol
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1,3-Dimethyluracil Chemical Properties

Melting point:
119-122 °C (lit.)
Boiling point:
256.63°C (rough estimate)
Density 
1.2850 (rough estimate)
refractive index 
1.5010 (estimate)
storage temp. 
Sealed in dry,Room Temperature
form 
powder to crystal
pka
-2.04±0.20(Predicted)
color 
White to Almost white
Water Solubility 
almost transparency
BRN 
124074
InChIKey
JSDBKAHWADVXFU-UHFFFAOYSA-N
CAS DataBase Reference
874-14-6(CAS DataBase Reference)
NIST Chemistry Reference
2,4(1H,3H)-Pyrimidinedione, 1,3-dimethyl-(874-14-6)
EPA Substance Registry System
2,4(1H,3H)-Pyrimidinedione, 1,3-dimethyl- (874-14-6)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36-36/37/38
Safety Statements 
22-24/25-39-26-36/37
WGK Germany 
3
TSCA 
Yes
HS Code 
29335990

MSDS

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1,3-Dimethyluracil Usage And Synthesis

Chemical Properties

white to light yellow needles

Uses

1,3-Dimethyluracil is suitable reagent used to investigate the steady-state absorption and fluorescence spectra of uracil derivatives. It may be used in the preparation of 2,6-dihydroxynicotinamide.

Definition

ChEBI: 1,3-dimethyluracil is a pyrimidone that is uracil with methyl group substituents at positions 1 and 3. It has a role as a metabolite. It is functionally related to a uracil.

General Description

1,3-Dimethyluracil is a pyrimidine derivative. Stability of the C6-centered carbanions derived from 1,3-dimethyluracil has been investigated in the gas phase and in DMSO and water solutions. The excited state structural dynamics of 1,3-dimethyluracil (DMU) in water and acetonitrile has been studied by resonance Raman spectroscopy. Crystal structure of 1,3-dimethyluracil has been reported. Ultraviolet irradiation of aqueous 1,3-dimethyluracil results in hydration of the 5:6 double bond of the uracil ring to form 1,3-dimethyl-6-oxy-hydrouracil.

Purification Methods

Crystallise it from EtOH/ether. [Beilstein 24 III/IV 1196.]

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