ANILINE-D7 Chemical Properties

Melting point:

-6 °C(lit.)

Boiling point:

184 °C(lit.)

Density 

1.098 g/mL at 25 °C

refractive index 

n20/D 1.5824(lit.)

Flash point:

158 °F

storage temp. 

2-8°C

Stability:

Stable, but light sensitive. May discolour upon exposure to air or light. Incompatible with oxidizing agents, bases, iron, iron salts, aluminium, zinc.

InChI

1S/C6H7N/c7-6-4-2-1-3-5-6/h1-5H,7H2/i1D,2D,3D,4D,5D/hD2

InChIKey

PAYRUJLWNCNPSJ-LQHBDRBESA-N

SMILES

[2H]N([2H])c1c([2H])c([2H])c([2H])c([2H])c1[2H]

EPA Substance Registry System

Aniline-d7 (14545-23-4)

CAS Number Unlabeled

62-53-3

Safety Information

Hazard Codes 

T,N

Risk Statements 

20/21/22-40-48/23/24/25-50-68-43-41-23/24/25

Safety Statements 

28-36/37-45-61-36/37/39-26-63-46-27

RIDADR 

UN 1547 6.1/PG 2

WGK Germany 

3

HS Code 

28459000

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials

Hazard Classifications

Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Aquatic Acute 1
Aquatic Chronic 1
Carc. 2
Eye Dam. 1
Muta. 2
Skin Sens. 1
STOT RE 1

MSDS

• Language:English Provider:SigmaAldrich

ANILINE-D7 Usage And Synthesis

Chemical Properties

colourless to light yellow liquid

Uses

Aniline-d7 is used in the manufacture of dyes, medicinals, resins, varnishes, perfumes, as a vulcanizing rubber or even as a solvent. This is the deuterium labeled analog.

Synthesis

Aniline-d7 was prepared as follows: in the reaction flask add aniline 10mmol, heavy water 20mL and SOCl20.3mL in turn, reflux reaction 24h. cooled to room temperature, TLC detected the reaction was complete [unfolding agent: A = V (ethyl acetate): V (petroleum ether) = 1:10], with saturated sodium bicarbonate solution to pH 7, with ethyl acetate (3?? 20mL) Extracted with ethyl acetate (3??20mL), the organic layers were combined, washed with saturated saline (2??15mL), dried with anhydrous Na2SO4, filtered, and the filtrate was concentrated and then purified by silica gel column chromatography (eluent: A=1:20) to obtain deuterated aniline (Aniline-d7).

ANILINE-D7(14545-23-4)Related Product Information

• 2-(4'-CHLOROPHENOXY)ANILINE,2-(4-CHLOROPHENOXY)ANILINE
• 2,4-BIS(TRIFLUOROMETHYL)ANILINE
• 2,4-DICHLORO-5-(2-PROPYLOXY)ANILINE
• ANILINE-D7
• ANILINE D5
• 2,4,6-TRIS(TRIFLUOROMETHYL)ANILINE
• D-Phenylalanine
• 2,4-DICHLORO-6-(TRIFLUOROMETHYL)ANILINE
• 1-(4-BROMOPHENYL)ANILINE
• 2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)ANILINE
• 2-(4-CHLOROPHENYLTHIO)ANILINE
• 2,4-DIBROMO-6-(TRIFLUOROMETHYL)ANILINE
• DEUTERIUM
• 2-(4-CHLOROPHENOXY)-5-(TRIFLUOROMETHYL)ANILINE
• METHYLAMINE-N,N-D2
• ANILINE-N,N-D2
• 2-(3-METHOXYPROPOXY)-5-(TRIFLUOROMETHYL)ANILINE
• 2-(4-BENZYLPHENOXY)-5-(TRIFLUOROMETHYL)ANILINE