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Rhodium(II) octanoate dimer

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Rhodium(II) octanoate dimer Basic information

Product Name:
Rhodium(II) octanoate dimer
Synonyms:
  • RHODIUM(III)OCTANOATE DIMER
  • RHODIUM (II) OCTANOATE DIMER
  • RHODIUM OCTANOATE DIMER
  • Rhodium(II)octanoatedimer,98%
  • Rhodiumoctanoatedimergreenpowder
  • Rh26%Dirhodium tetraoctanoate
  • Dirhodium tetraoctanoate
  • Rhodium(II)octanoate
CAS:
73482-96-9
MF:
C32H60O8Rh2
MW:
778.64
EINECS:
247-015-0
Product Categories:
  • Rh
  • chemical reaction,pharm,electronic,materials
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Rhodium
  • metal carboxylate
  • RhodiumMicro/Nanoelectronics
  • Solution Deposition Precursors
Mol File:
73482-96-9.mol
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Rhodium(II) octanoate dimer Chemical Properties

Melting point:
289-292°C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Soluble in hot alcohol, dichloromethane, toluene and acetic acid, slightly soluble in alcohol
form 
Powder
color 
Green
InChI
InChI=1S/4C8H16O2.2Rh/c4*1-2-3-4-5-6-7-8(9)10;;/h4*2-7H2,1H3,(H,9,10);;/q;;;;2*+2/p-4
InChIKey
NTRXCIBAMWRBPL-UHFFFAOYSA-N
SMILES
C(C1=O[Rh+2]234O=C(CCCCCCC)[O-][Rh+2]2(O=C(CCCCCCC)[O-]3)(O=C(CCCCCCC)[O-]4)[O-]1)CCCCCC
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
28439000

MSDS

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Rhodium(II) octanoate dimer Usage And Synthesis

Chemical Properties

Green Powder

Uses

Rhodium(II) Octanoate Dimer is a catalyst which is used in intramolecular cyclization of 1-sulfonyl-1,2,3-triazole and sulfinate.

Preparation

Rhodium(II) octanoate dimer can be prepared by ligand substitution from Rh2(OAc)4.

reaction suitability

reaction type: C-H Activation
reagent type: catalyst

storage

air stable, weakly hygroscopic; stored in desiccator

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