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trans-Dichlorodiamineplatinum(II)

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trans-Dichlorodiamineplatinum(II) Basic information

Product Name:
trans-Dichlorodiamineplatinum(II)
Synonyms:
  • trans-Diamminedichloroplatinum(II), Pt 64.5% min
  • trans-Diamminedichloroplatinum(II), trans-Dichlorodiammineplatinum(II)
  • Transplatin (25 mg)
  • trans-Dichlorodiamineplatinum(II)trans-DDPTransplatin
  • trans-DichlorodiaMineplatinuM(II), 99.95%, (trace Metal basis)
  • LEDERPLATIN
  • BRIPLATIN
  • DIAMMINEDICHLOROPLATINATE (II)
CAS:
14913-33-8
MF:
Cl2H4N2Pt
MW:
298.03
EINECS:
238-980-9
Product Categories:
  • Anticancer
  • metal-ammine complexes
  • chemical reaction,pharm,electronic,materials
  • Impurities
  • Intermediates & Fine Chemicals
  • Pharmaceuticals
  • Materials Science
  • Metal and Ceramic Science
  • Platinum Salts
  • Salts
Mol File:
14913-33-8.mol
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trans-Dichlorodiamineplatinum(II) Chemical Properties

Melting point:
340 °C (dec.)(lit.)
storage temp. 
2-8°C
solubility 
DMSO (Sparingly)
form 
crystalline
color 
yellow
Water Solubility 
Soluble in dimethylsulfoxide and dimethylformamide. Slightly soluble in water.
Exposure limits
ACGIH: TWA 0.002 mg/m3
NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3
EPA Substance Registry System
Platinum, diamminedichloro-, (SP-4-1)- (14913-33-8)
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Safety Information

Hazard Codes 
T,Xn
Risk Statements 
45-25-41-68-42/43-40-23/24/25
Safety Statements 
53-26-39-45-36/37-24-23
RIDADR 
UN 3288 6.1/PG 2
WGK Germany 
3
RTECS 
TP2455000
10-21
HazardClass 
6.1(a)
PackingGroup 
II
HS Code 
28439000
Hazardous Substances Data
14913-33-8(Hazardous Substances Data)
Toxicity
mouse,LD50,intraperitoneal,27mg/kg (27mg/kg),Chemico-Biological Interactions. Vol. 5, Pg. 415, 1972.

MSDS

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trans-Dichlorodiamineplatinum(II) Usage And Synthesis

Chemical Properties

Yellow Powder or Crystal

Uses

Transplatin is the trans stereoisomer impurity of Cisplatin (C499500), an antineoplastic used in the treatment of sarcomas, some carcinomas, lymphomas, and germ cell tumors. Transplatin binds to DNA but does not exhibit the same useful pharmacological effect as its cis stereoisomer.

Uses

Transplatin is the trans stereoisomer impurity of trans-Dichlorodiamineplatinum(II), an antineoplastic used in the treatment of sarcomas, some carcinomas, lymphomas, and germ cell tumors. Transplatin binds to DNA but does not exhibit the same useful pharmacological effect as its cis stereoisomer.

Definition

ChEBI: A diamminedichloroplatinum compound in which the two ammine ligands and two chloro ligands are oriented in a trans planar configuration around the central platinum ion. Unlike its cis-isomer, cisplatin, it does not exhibit any useful pharmacological effect and is toxic.

Safety Profile

Poison by intraperitoneal route. Questionable carcinogen with experimental tumorigenic data. Human mutation data reported. See also PLATINUM COMPOUNDS. When heated to decomposition it emits toxic fumes of NOx and Cl-.

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