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Bis(triphenylphosphinepalladium) acetate

Basic information Safety Supplier Related

Bis(triphenylphosphinepalladium) acetate Basic information

Product Name:
Bis(triphenylphosphinepalladium) acetate
Synonyms:
  • Diacetatobis(triphenylphosphine)palladium(II) Store refrigerated
  • Bis(acetato)bis(triphenylphosphine)palladium(II), Palladium(II)bis(triphenylphosphine) diacetate
  • Palladium, bis(acetato-O)bis(triphenylphosphine)-
  • Diacetatobis(triphenylphosphine)palladium(II), Pd 14.2%
  • Diacetatobis(Triphenylphosphosphate) PalladiuM
  • Bis(triphenylphosphine)palladium(II) acetate,99%
  • Diacetatobis(triphenylphosphine)palladiuM(II),98% (PPh3)2Pd(OAc)2
  • Bis(triphenylphosphinepalladiu
CAS:
14588-08-0
MF:
C40H36O4P2Pd
MW:
749.08
EINECS:
238-628-4
Product Categories:
  • metal-phosphine complexes
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Pd (Palladium) Compounds
  • Metal Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • chemical reaction,pharm,electronic,materials
  • Halogenated Heterocycles ,Pyrimidines
  • Pd
Mol File:
14588-08-0.mol
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Bis(triphenylphosphinepalladium) acetate Chemical Properties

Melting point:
136 °C (dec.)(lit.)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
form 
Powder
color 
Yellow
Stability:
store cold
InChI
InChI=1S/2C18H15P.2C2H4O2.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-2(3)4;/h2*1-15H;2*1H3,(H,3,4);/q;;;;+2/p-2
InChIKey
OZELLBKLLRMCRL-UHFFFAOYSA-M
SMILES
P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1C=CC=CC=1)(C1=CC=CC=C1)C1=CC=CC=C1.O(C(=O)C)[Pd]OC(=O)C
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Safety Information

Hazard Codes 
Xn
Safety Statements 
22-24/25
WGK Germany 
3
1-3-10
HS Code 
28439000

MSDS

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Bis(triphenylphosphinepalladium) acetate Usage And Synthesis

Chemical Properties

yellow powder

Uses

suzuki reaction

Uses

Bis(triphenylphosphine)palladium(II) diacetate can be used as a catalyst for C-C bond formation via Sonogashira coupling, Negishi coupling, Heck coupling, and Suzuki coupling reaction.
It can also be used as a catalyst to synthesize:

  • Pyrido[1,2-a]benzimidazole derivatives by electro-oxidative intramolecular C-H/N-H annulation reaction.
  • α, β-Unsaturated carboxylic acids by hydroxycarbonylation of vinyl triflates.
  • Secondary imides by C-H functionalization of aldehydes with different N-substituted N-heteroarene-2-carboxamides.

Bis(triphenylphosphinepalladium) acetateSupplier

Shaanxi Rock New Materials Co., Ltd. Gold
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0917-8888777, 3380777,18691786767; 15619786767
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J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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021-67121386
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Sales-CN@TCIchemicals.com