9-(3-bromophenyl)carbazole Chemical Properties

Melting point:

69-70℃

Boiling point:

463℃

Density 

1.39

Flash point:

234℃

storage temp. 

Sealed in dry,Room Temperature

form 

powder to crystal

color 

White to Almost white

InChI

InChI=1S/C18H12BrN/c19-13-6-5-7-14(12-13)20-17-10-3-1-8-15(17)16-9-2-4-11-18(16)20/h1-12H

InChIKey

ZKGHGKNHPPZALY-UHFFFAOYSA-N

SMILES

N1(C2=CC=CC(Br)=C2)C2=C(C=CC=C2)C2=C1C=CC=C2

Safety Information

HS Code 

2933.99.8290

9-(3-bromophenyl)carbazole Usage And Synthesis

Chemical Properties

White solid

Uses

9-(3-bromophenyl)carbazole can be used to synthesize organic optoelectronic materials.

Hazard

9-(3-bromophenyl)carbazole can cause skin irritation and serious eye irritation.

Synthesis

1-bromo-3-iodobenzene, 2.02 mL (15.8mmol), copper (Cu) 2.29 g (36.0 mmol) of calcium carbonate and 4.98 g (36.0 mmol) of DMF in 30 mL insert heated at 130 It was stirred. After the completion of the reaction, it cooled to ambient temperature, diluted with ethyl acetate to a vacuum filter, and passed through a silica gel. The filtrate was concentrated under reduced pressure. Separating the product by silica gel column chromatography (ethyl acetate: n-hexane = 1: 20) to give 9-(3-bromophenyl)carbazole 3.80 g (98 per cent yield).

References

[1] Patent: KR101593182, 2016, B1. Location in patent: Paragraph 0427; 0430; 0438; 0439
[2] Patent: CN107686484, 2018, A. Location in patent: Paragraph 0123-0128
[3] Patent: KR101622443, 2016, B1. Location in patent: Paragraph 0109; 0110
[4] RSC Advances, 2015, vol. 5, # 64, p. 51512 - 51523
[5] Patent: WO2012/4765, 2012, A2. Location in patent: Page/Page column 73-74

9-(3-bromophenyl)carbazole(185112-61-2)Related Product Information

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