XPhos Pd G2
XPhos Pd G2 Basic information
- Product Name:
- XPhos Pd G2
- Synonyms:
-
- Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl) palladiuM(II), Min. 98% [XPhos Palladacycle]
- Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2'-aMino-1,1'-biphenyl)]palladiuM(II)
- Chloro(2-dicyclohexylphosphin
- (SP-4-4)-[2'-Amino[1,1'-biphenyl]-2-yl]chloro[dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine]palladium
- 2nd Generation XPhos Precatalyst
- X-Phos aminobiphenyl palladium chloride precatalyst
- Palladium-Xphos
- -biphenyl-2-yl) palladium(II), min. 98%
- CAS:
- 1310584-14-5
- MF:
- C45H58ClNPPd+2
- MW:
- 785.795481
- Product Categories:
-
- Pd
- Buchwald Ligands&Precatalysts
- Buchwald Precatalysts Series
- Mol File:
- 1310584-14-5.mol
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XPhos Pd G2 Chemical Properties
- Melting point:
- 202-210°C
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- color
- white
- InChI
- InChI=1S/C33H48ClP.C12H10N.Pd/c1-22(2)25-20-29(23(3)4)32(30(21-25)24(5)6)28-18-13-19-31(34)33(28)35(26-14-9-7-10-15-26)27-16-11-8-12-17-27;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;/h13,18-24,26-27H,7-12,14-17H2,1-6H3;1-6,8-9H,13H2;/q;;+2
- InChIKey
- USWOVTRTHZODCW-UHFFFAOYSA-N
- SMILES
- C1(C2=CC=CC=C2N)=CC=CC=C1[Pd+2].C1(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)=CC=CC(Cl)=C1P(C1CCCCC1)C1CCCCC1
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XPhos Pd G2 Usage And Synthesis
Appearance
Turquoise or grey or dark green powder
Reaction
Palladium precatalyst for Suzuki-Miyaura coupling reactions.
Uses
XPhos Pd G2 is a used as a catalyst in chemical reactions.
Uses
XPhos Pd G2 was employed as catalyst in the following reactions:
- Palladium-catalyzed Suzuki-Miyaura coupling reactions of potassium organotrifluoroborates and sulfamates.
- Suzuki-Miyaura cross-coupling reactions of sensitive aryl and heteroarylboronic acids.
- Synthesis of potassium Boc-protected secondary aminomethyltrifluoroborates, via Suzuki-Miyaura cross-coupling reaction.
Application
XPhos Pd G2 is a second-generation Buchwald catalyst typically used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions.
General Description
XPhos Pd G2 is a bulky monodentate biaryl ligand. It is a Buchwald′s 2nd generation preformed catalyst. It undergoes rapid reductive elimination to form a reactive, monoligated Pd(0) species.
XPhos Pd G2Supplier
Henan Runfeng Catalyst Co. LTD Gold
- Tel
- 15560227177
- sales@runcatalysts.cn
WuHan Taiyukaishang Chemical Co., Ltd. Gold
- Tel
- 027-87680032 18963957250
- 355723431@qq.com
Beijing Guofang Dingsheng Technology Co., Ltd. Gold
- Tel
- 18610472091 18610472091
- gfdskj@163.com
Wu Han Lbpchem Chemical Co., Ltd. Gold
- Tel
- 02763499399 13797220777
- lpbchem@163.com
Wuhan phosphine biologic Pharmaceutical Co., LTD Gold
- Tel
- 15102702255 15102702255
- 35729423@qq.com
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XPhos Pd G2(1310584-14-5)Related Product Information
- XPhos Pd G3
- XPhos Pd G4
- Chloro(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [BrettPhos Palladacycle]
- BrettPhos Pd G3
- RuPhos Pd G1 Methyl t--Butyl Ether Adduct
- BrettPhosPalladacycle
- Palladacycle Gen. 3
- t-BuXphos Palladacycle Gen. 4
- RuPhos Palladacycle Gen. 4
- t-BuBrettPhos Palladacycle Gen. 3
- SPhos Pd G3
- SPhos Pd G1, Methyl t-Butyl Ether Adduct
- RuPhos Pd G2
- tBuXPhos Pd G1
- XPhos Pd G1
- RuPhos Pd G3
- Bis(diphenylphosphinophenyl)ether palladium (II) dichloride
- Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)