XPhos Pd G2 Chemical Properties

Melting point:

202-210°C

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

form 

Powder

color 

white

InChI

InChI=1S/C33H48ClP.C12H10N.Pd/c1-22(2)25-20-29(23(3)4)32(30(21-25)24(5)6)28-18-13-19-31(34)33(28)35(26-14-9-7-10-15-26)27-16-11-8-12-17-27;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;/h13,18-24,26-27H,7-12,14-17H2,1-6H3;1-6,8-9H,13H2;/q;;+2

InChIKey

USWOVTRTHZODCW-UHFFFAOYSA-N

SMILES

C1(C2=CC=CC=C2N)=CC=CC=C1[Pd+2].C1(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)=CC=CC(Cl)=C1P(C1CCCCC1)C1CCCCC1

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26

WGK Germany 

3

XPhos Pd G2 Usage And Synthesis

Appearance

Turquoise or grey or dark green powder

Reaction

Palladium precatalyst for Suzuki-Miyaura coupling reactions.

Uses

XPhos Pd G2 is a used as a catalyst in chemical reactions.

Uses

XPhos Pd G2 was employed as catalyst in the following reactions:

• Palladium-catalyzed Suzuki-Miyaura coupling reactions of potassium organotrifluoroborates and sulfamates.
• Suzuki-Miyaura cross-coupling reactions of sensitive aryl and heteroarylboronic acids.
• Synthesis of potassium Boc-protected secondary aminomethyltrifluoroborates, via Suzuki-Miyaura cross-coupling reaction.

Application

XPhos Pd G2 is a second-generation Buchwald catalyst typically used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions. 

General Description

XPhos Pd G2 is a bulky monodentate biaryl ligand. It is a Buchwald′s 2^nd generation preformed catalyst. It undergoes rapid reductive elimination to form a reactive, monoligated Pd(0) species.

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

XPhos Pd G2(1310584-14-5)Related Product Information

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