ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic rhodium > (+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE Basic information
- Product Name:
- (+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
- Synonyms:
-
- (+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(l)tetrafluroborate
- (+)-Bisdiethylphospholanobenzenecyclooctadienerhod
- (+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(S,S)-Et-DUPHOS-Rh
- 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
- (+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) tetrafluroborate
- (+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Et-DUPHOS-Rh
- 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate
- (+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
- CAS:
- 213343-64-7
- MF:
- C30H46BF4P2Rh
- MW:
- 658.35
- Product Categories:
-
- organometallic complex
- Mol File:
- 213343-64-7.mol
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(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE Chemical Properties
- form
- Powder
- color
- Orange to red to brown
- Sensitive
- air sensitive
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Safety Information
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- WGK Germany
- 3
- HS Code
- 28439000
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(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE Usage And Synthesis
Reactions
- Ligand used in asymmetric hydrogenation of 2-methylenesuccinamic acid.
- Ligand used for the Rh-catalyzed asymmetric hydrogenation of α-aminomethylacrylates.
Chemical Properties
Dark orange-red solid
Uses
(S,S)-Et-DUPHOS-Rh is a catalyst in the asymmetric preparation of B precursor of cryptophycin, and in the synthesis of constrained phenylalanine analogs.
Uses
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
Catalyst for:
- Preparation of a key unit B precursor of cryptophycins via Horner-Wadsworth-Emmons reaction and asymmetric hydrogenation
- Preparation of constrained phenylalanine analogs via Heck reaction followed by asymmetric hydrogenation and cyclization steps
- Enantioselective preparation of N-benzyloxy-β-amino acid Me esters by hydrogenation of α-(benzyloxyaminomethyl)acrylate stereoisomers
- Preparation of fluoro amino acids as synthons for potent macrocyclic HCV NS3 protease inhibitors
- Stereoselective preparation of triply isotope-labeled Ser, Cys, and Ala
- Preparation of β-amino acids from asymmetric hydrogenation of α-(aminomethyl)acrylates
- Asymmetric hydrogenation of a-primary and secondary amino ketones and asymmetric synthesis of (-)-arbutamine and (-)-denopamine
(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATESupplier
J & K SCIENTIFIC LTD.
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- 010-82848833 400-666-7788
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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- 021-61259108 18621169109
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Alfa Aesar
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- 400-6106006
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Energy Chemical
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- 021-021-58432009 400-005-6266
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Daicel Chiral Technologies (China)CO.,LTD
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- 021-50460086-9 15921403865
- han_yajun@dctc.daicel.com
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(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE(213343-64-7)Related Product Information
- Benzene
- (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
- (+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE
- (+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE
- (+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
- (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE
- 1,2-BIS(PHOSPHINO)BENZENE
- (+)-1,2-BIS((2R,5R)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE)1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE