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PHENYL VINYL SULFOXIDE

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PHENYL VINYL SULFOXIDE Basic information

Product Name:
PHENYL VINYL SULFOXIDE
Synonyms:
  • (Vinylsulfinyl)benzene
  • Sulfoxide, phenyl vinyl
  • PHENYL VINYL SULFOXIDE
  • phenyl vinyl sulphoxide
  • Benzene, (ethenylsulfinyl)-
  • NISTC20451530
  • VINYL PHENYL SULFOXIDE
  • (Ethenylsulfinyl)benzene
CAS:
20451-53-0
MF:
C8H8OS
MW:
152.21
EINECS:
243-831-6
Product Categories:
  • Organic Building Blocks
  • Sulfoxides
  • Sulfur Compounds
Mol File:
20451-53-0.mol
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PHENYL VINYL SULFOXIDE Chemical Properties

Boiling point:
93-95 °C/0.2 mmHg (lit.)
Density 
1.139 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.585(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
form 
liquid
color 
deeply yellow
BRN 
2039218
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Safety Information

Hazard Codes 
Xi
Risk Statements 
41
Safety Statements 
24/25-39-26
WGK Germany 
3
HS Code 
2930909899

MSDS

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PHENYL VINYL SULFOXIDE Usage And Synthesis

Synthesis Reference(s)

The Journal of Organic Chemistry, 61, p. 2260, 1996 DOI: 10.1021/JO960178X

General Description

Phenyl vinyl sulfoxide reacts with lithium enolates of ketones at -78°C in THF to yield bicyclo[n.2.0]alkan-1-ols. It also reacts with in situ generated (dialkylamino)magnesium reagent to yield symmetrical β-(dialkylamino)dithioacetals. It participates as an acetylene equivalent in Diels-Alder reactions.

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