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ChemicalBook >  Product Catalog >  Chemical Reagents >  Organic reagents >  Phosphine ligand >  (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Basic information

Product Name:
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
Synonyms:
  • (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
  • (11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
  • N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE
  • N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE
  • (R)-SIPHOS
  • (S)-SIPHOS
  • (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine,min.98%(S)-SIPHOS
  • N-DIMETHYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (S)-SIPHOS
CAS:
443965-10-4
MF:
C19H20NO2P
MW:
325.34
Product Categories:
  • Chiral Phosphine
  • Chiral Spiro Ligand
  • CPN
Mol File:
443965-10-4.mol
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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Chemical Properties

Melting point:
95-96°C
Boiling point:
429.6±55.0 °C(Predicted)
alpha 
-502° (c 0.5, CH2Cl2)
storage temp. 
-20°C
pka
2.19±0.20(Predicted)
form 
solid
color 
white
Sensitive 
moisture sensitive
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Safety Information

HS Code 
29252900
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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Usage And Synthesis

Reaction

  1. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of α-dehydroamino esters.
  2. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of itaconic acid derivatives.
  3. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of β-dehydroaminoesters.
  4. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of enamides.
  5. Chiral ligands for rhodium-catalyzed asymmetric Pauson-Khand reaction.
  6. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes. 


Chemical Properties

White to light yellow powder

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Preparation Products And Raw materials

Raw materials

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINESupplier

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