ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Phosphine ligand > (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Basic information
- Product Name:
- (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
- Synonyms:
-
- (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
- (11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
- N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE
- N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE
- (R)-SIPHOS
- (S)-SIPHOS
- (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine,min.98%(S)-SIPHOS
- N-DIMETHYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (S)-SIPHOS
- CAS:
- 443965-10-4
- MF:
- C19H20NO2P
- MW:
- 325.34
- Product Categories:
-
- Chiral Phosphine
- Chiral Spiro Ligand
- CPN
- Mol File:
- 443965-10-4.mol
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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Chemical Properties
- Melting point:
- 95-96°C
- Boiling point:
- 429.6±55.0 °C(Predicted)
- alpha
- -502° (c 0.5, CH2Cl2)
- storage temp.
- -20°C
- pka
- 2.19±0.20(Predicted)
- form
- solid
- color
- white
- Sensitive
- moisture sensitive
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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Usage And Synthesis
Reaction
- Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of α-dehydroamino esters.
- Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of itaconic acid derivatives.
- Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of β-dehydroaminoesters.
- Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of enamides.
- Chiral ligands for rhodium-catalyzed asymmetric Pauson-Khand reaction.
- Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
Chemical Properties
White to light yellow powder
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Preparation Products And Raw materials
Raw materials
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINESupplier
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
BeiJing Hwrk Chemicals Limted
- Tel
- 0757-86329057 18934348241
- sales4.gd@hwrkchemical.com
Daicel Chiral Technologies (China)CO.,LTD
- Tel
- 021-50460086-9 15921403865
- han_yajun@dctc.daicel.com
Tianjin Derchemist Science & Technology Co., Ltd.
- Tel
- 22-58627059 13920586291
- zdcomcon@126.com
Shanghai Chiral bio-compound co., Ltd.
- Tel
- 021-5068 3667/17749785980/1029026415; 17749785980
- 1029026415@qq.com
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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE(443965-10-4)Related Product Information
- Indene
- Dimethylamine
- (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
- (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE
- (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE