BIS(PENTAFLUOROPHENYL)CARBONATE Chemical Properties

Melting point:

47-50 °C(lit.)

Boiling point:

250°C

Density 

1.782±0.06 g/cm3(Predicted)

Flash point:

110 °C

storage temp. 

Sealed in dry,Room Temperature

solubility 

Soluble in chloroform, ethyl acetate and methylene chloride.

form 

powder to crystal

color 

White to Almost white

BRN 

2029727

Major Application

peptide synthesis

InChI

InChI=1S/C13F10O3/c14-1-3(16)7(20)11(8(21)4(1)17)25-13(24)26-12-9(22)5(18)2(15)6(19)10(12)23

InChIKey

IOVVFSGCNWQFQT-UHFFFAOYSA-N

SMILES

O(C1C(=C(F)C(F)=C(F)C=1F)F)C(=O)OC1C(=C(F)C(F)=C(F)C=1F)F

CAS DataBase Reference

59483-84-0(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

22-24/25

WGK Germany 

3

HazardClass 

IRRITANT

HS Code 

29209090

Storage Class

11 - Combustible Solids

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich

BIS(PENTAFLUOROPHENYL)CARBONATE Usage And Synthesis

Chemical Properties

White crystalline powder and chunks

Uses

Bis(pentafluorophenyl) carbonate is a reagent used as a carbonyl equivalent and for various coupling reactions, especially for azapeptides.

Uses

Bis(pentafluorophenyl) carbonate can be used in the preparation of:

• A cyclic carbonate named 6,6′-(ethane-1,2-diyl)bis(1,3,6-dioxazocan-2-one), which is a key intermediate for the synthesis of non-isocyanate polyurethanes.
• A coumarin based aliphatic polycarbonate named 5-(4-methylumbelliferyloxycarbonyl)-5-methyl-1,3-dioxan-2-one (MUC).

General Description

Bis(pentafluorophenyl) carbonate is the equivalent of carbonyl compound generally used in coupling reactions. It is used as a reagent in the preparation of azapeptides.

reaction suitability

reaction type: Carbonylations

BIS(PENTAFLUOROPHENYL)CARBONATE(59483-84-0)Related Product Information

• [Bis(trifluoroacetoxy)iodo]benzene
• Bis(diphenylphosphinophenyl)ether palladium (II) dichloride
• Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)
• Bis(acetonitrile)dichloropalladium(II)
• DICHLOROBIS(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II)
• Bis(2-dicyclohexylphosphinophenyl)ether, 98%
• Bis(dibenzylideneacetone)palladium
• BIS(DICYCLOHEXYLPHOSPHINO)METHANE
• Benzotriazole-1-yl-oxytripyrrolidinophosphonium hexafluorophosphate
• Diphenyl carbonate
• 1-FLUORO-3-(METHOXYMETHOXY)BENZENE
• BIS(PENTAFLUOROPHENYL)CARBONATE
• METHYL PENTAFLUOROPHENYL CARBONATE
• DIPHENOXYMETHANE
• 2,5-Difluoro-1-(methoxymethoxy)Benzene