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2-Bromo-5-methoxytoluene

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2-Bromo-5-methoxytoluene Basic information

Product Name:
2-Bromo-5-methoxytoluene
Synonyms:
  • 2-Bromo-5-methoxytoluene, 1-Bromo-4-methoxy-2-methylbenzene, 4-Bromo-3-methylphenyl methyl ether
  • 2-BroMo-5-Methoxytoluene (BMA)
  • 4-BroMo-3-Methylanisole, 97%, 97%
  • 2-Bromo-4-methoxy-1-methylbenzene
  • 1-BROMO-4-METHOXY-2-METHYLBENZENE
  • 2-BROMO-5-METHOXYTOLUENE
  • 2-(3-bromophenyl)-2-methoxyacetic acid
  • 3-Methyl-4-bromoanisole
CAS:
27060-75-9
MF:
C8H9BrO
MW:
201.06
Product Categories:
  • Halogen toluene
  • Anisoles, Alkyloxy Compounds & Phenylacetates
  • Aromatic Hydrocarbons (substituted) & Derivatives
  • Bromine Compounds
Mol File:
27060-75-9.mol
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2-Bromo-5-methoxytoluene Chemical Properties

Melting point:
16.5 °C
Boiling point:
111-112 °C15 mm Hg(lit.)
Density 
1.424 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.561(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
water: soluble (Partially miscible)(lit.)
form 
Liquid
Specific Gravity
1.424
color 
Clear colorless to slightly yellow
FreezingPoint 
12.0 to 16.0 ℃
BRN 
1933865
CAS DataBase Reference
27060-75-9(CAS DataBase Reference)
NIST Chemistry Reference
2-Bromo-5-methoxytoluene(27060-75-9)
EPA Substance Registry System
2-Bromo-5-methoxytoluene (27060-75-9)
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Safety Information

Hazard Codes 
Xi
Safety Statements 
24/25
WGK Germany 
3
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29093090

MSDS

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2-Bromo-5-methoxytoluene Usage And Synthesis

Chemical Properties

colorless to light yellow liquid

Uses

2-bromo-5-methoxytoluene could be used to syntheis 4-bromo-3-(bromomethyl)anisole. In specifically, to a CCl4 solution (125 mL) of 2-bromo-5-methoxytoluene (0.050 mol) and NBS (0.055 mol) was added AIBN (0.001 mol), and the mixture was stirred at 80 °C for 18 h. The mixture was diluted with hexane before filtration through a Celite pad. Evaporation of the solvent and washing the residue with ethyl acetate gave 4-bromo-3-(bromomethyl)anisole.

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