Basic information Safety Supplier Related

1-Methyl-2-phenylindole

Basic information Safety Supplier Related

1-Methyl-2-phenylindole Basic information

Product Name:
1-Methyl-2-phenylindole
Synonyms:
  • 1-methyl-2-phenyl-1h-indol
  • 1-METHYL-2-PHENYLINDOLE
  • 1-METHYL-2-PHENYL-1H-INDOLE
  • N-METHYL-2-PHENYLINDOLE
  • 1-Methyl-2-Phenylindol
  • 1-METHYL-2-PHENYLINDOLE 99+%
  • 1H-Indole, 1-methyl-2-phenyl-
  • 2-Phenyl-N-methylindole
CAS:
3558-24-5
MF:
C15H13N
MW:
207.27
EINECS:
222-618-1
Product Categories:
  • Heterocycle-Indole series
  • Intermediates of Dyes and Pigments
  • Indole
  • Indoles
  • Simple Indoles
  • Building Blocks
  • Heterocyclic Building Blocks
  • intermediates
Mol File:
3558-24-5.mol
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1-Methyl-2-phenylindole Chemical Properties

Melting point:
98-100 °C (lit.)
Boiling point:
336.3°C (rough estimate)
Density 
1.0880 (rough estimate)
refractive index 
1.5720 (estimate)
storage temp. 
2-8°C
form 
powder to crystal
color 
White to Light yellow
BRN 
148770
InChI
InChI=1S/C15H13N/c1-16-14-10-6-5-9-13(14)11-15(16)12-7-3-2-4-8-12/h2-11H,1H3
InChIKey
SFWZZSXCWQTORH-UHFFFAOYSA-N
SMILES
N1(C)C2=C(C=CC=C2)C=C1C1=CC=CC=C1
CAS DataBase Reference
3558-24-5(CAS DataBase Reference)
EPA Substance Registry System
1H-Indole, 1-methyl-2-phenyl- (3558-24-5)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
24/25-26
WGK Germany 
3
TSCA 
Yes
HS Code 
29339900

MSDS

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1-Methyl-2-phenylindole Usage And Synthesis

Chemical Properties

WHITE TO LIGHT GREEN-TAN CRYSTALS OR CRYST. POWDER

Uses

Reactant for preparation of:

  • Cyano indoles
  • Difluorohydroxy indoles

Reactant for:
  • Carboxylation of indoles
  • Allylation of indoles
  • Formylation of indoles
  • Nitrosylation of indoles

Synthesis Reference(s)

Tetrahedron Letters, 34, p. 2059, 1993 DOI: 10.1016/S0040-4039(00)60345-3

General Description

Reaction of 1-methyl-2-phenylindole with nitrogen dioxide or with nitrous acid (NaNO2-CH3COOH) in benzene has been studied. 1-Methyl-2-phenylindole is reported to react with malondialdehyde (MDA) and 4-hydroxyalkenals to afford a stable chromophore with intense maximal absorbance at 586nm.

1-Methyl-2-phenylindole Preparation Products And Raw materials

Raw materials

Preparation Products

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