BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE Chemical Properties

Melting point:

236 °C (dec.) (lit.)

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

form 

Powder

color 

blue

Sensitive 

air sensitive

InChI

InChI=1S/2C18H15P.2ClH.Co/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

InChIKey

OPRPFIIIFJLFCE-UHFFFAOYSA-L

SMILES

P(C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Co](Cl)Cl

Safety Information

Hazard Codes 

Xn

Risk Statements 

20/21/22

Safety Statements 

36

WGK Germany 

3

MSDS

• Language:English Provider:SigmaAldrich

BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE Usage And Synthesis

Reaction

1. Catalyst used for hydrostannations.
2. Catalyst used for alkyne-dihalomethaneamine couplings. – an efficient route for propargylamines.
3. Cobalt-catalyzed transformation of alkynyl C-H bond: aldehyde-alkyne-amine coupling.

BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE(14126-40-0)Related Product Information

• Bis(tricyclohexylphosphine)nickel(II) chloride, 99%
• Bis(triphenylphosphine)nickel(II)chloride
• BIS(TRIPHENYLPHOSPHINE)NICKEL(II) BROMIDE
• DICHLOROBIS(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II)
• Bis(triphenylphosphinepalladium) acetate
• Bis(dibenzylideneacetone)palladium
• Bis(cyclopentadienyl)zirconium dichloride
• BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE
• Bis[Tris(2-methylphenyl)phosphine]palladium
• DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II)
• BIS(DI-TERT-BUTYLPHOSPHINO)METHANE
• dichlorobis(di-tert-butylphenylphosphine)palladium(II)
• COPPER(II) HEXAFLUORO-2,4-PENTANEDIONATE
• TRANS-DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II)
• Bis(tricyclohexylphosphine)palladium(0)
• BIS(CYCLOHEXYLSULFONYL)DIAZOMETHANE
• Cobalt chloride
• (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE