1,3-Bis(aminomethyl)benzene Chemical Properties

Melting point:

14°C

Boiling point:

265 °C745 mm Hg(lit.)

Density 

1.032 g/mL at 25 °C(lit.)

vapor pressure 

15 mm Hg ( 145 °C)

refractive index 

n20/D 1.571(lit.)

Flash point:

>230 °F

solubility 

Chloroform (Slightly), Methanol (Slightly)

form 

Liquid

pka

9.37±0.10(Predicted)

color 

Clear slightly yellow

Water Solubility 

Miscible

BRN 

1099911

LogP

0.18 at 25℃

CAS DataBase Reference

1477-55-0(CAS DataBase Reference)

NIST Chemistry Reference

1,3-Benzenedimethanamine(1477-55-0)

EPA Substance Registry System

m-Xylylenediamine (1477-55-0)

Safety Information

Hazard Codes 

T,C

Risk Statements 

21/22-23-34-43-52/53-20/22

Safety Statements 

26-36/37/39-45-61-28A

RIDADR 

UN 2735 8/PG 2

OEL

Ceiling: 0.1 mg/m3 [skin]

WGK Germany 

2

RTECS 

PF8970000

F 

2-9

HazardClass 

8

PackingGroup 

II

HS Code 

29215900

Hazardous Substances Data

1477-55-0(Hazardous Substances Data)

Toxicity

rabbit,LD50,skin,2gm/kg (2000mg/kg),"Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986Vol. 5, Pg. 638, 1986.

MSDS

• Language:English Provider:1,3-Bis(aminomethyl)benzene
• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS

1,3-Bis(aminomethyl)benzene Usage And Synthesis

Description

m-Xylene-α,α0-diamine is a colorless liquid.Molecular weight=136.22; Specific gravity (H2O:1)=1.032 at 25℃; Boiling point = 247.2℃; Freezing/Meltingpoint =15℃; Vapor pressure = 0.03 mmHg at 25℃; Flashpoint = 117℃. Hazard Identification (based on NFPA-704M Rating System): Health 3, Flammability 0, Reactivity 0.Soluble in water.

Chemical Properties

CLEAR SLIGHTLY YELLOW LIQUID

Chemical Properties

m-Xylene-α,α0-diamine is a colorless liquid.

Uses

Manufacture of polyamide fibers and resins, as a curing agent.

Uses

m-Xylylenediamine can be used:

• As a monomer for the synthesis of poly(vinylogous urethane) vitrimers.
• As a starting material for the synthesis of carbamate-protected multisubstituted bis-guanidine.
• For the synthesis of polyamides by catalytic dehydrogenation with diols.

General Description

Colorless liquid with an amine smell. Mp: 14.1°C; bp: 273°C . Water soluble.

Reactivity Profile

1,3-Bis(aminomethyl)benzene is combustible (Flash point 139°C). Incompatible with acids, acid chlorides, acid anhydrides.

Hazard

Moderately toxic by skin contact and ingestion. Mildly toxic by inhalation. A severe skin, eye, and gastrointestinal irritant.

Safety Profile

Moderately toxic by skin contact and ingestion. Mildly toxic by inhalation. A severe skin and eye irritant. When heated to decomposition it emits toxic fumes of NOx. Used to make polyamide fibers and resins and as a curing agent.

Potential Exposure

m-Xylene-α,α0-diamine is a source of m-xylene di-isocyanate and used as an intermediate in the manufacture of epoxy and polyamide resins.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least30 min, occasionally lifting upper and lower lids. Seekmedical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, getmedical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

storage

Color Code—White: Corrosive or Contact Hazard;Color Code—Blue: Health Hazard/Poison: Store in a securepoison location. Store separately in a corrosion-resistantlocation. Prior to working with this chemical you should betrained on its proper handling and storage. Store in tightlyclosed containers in a cool, well-ventilated area away fromoxidizers (such as perchlorates, peroxides, permanganates,chlorates, and nitrates) and strong acids (such as hydrochloride, sulfuric, and nitric). Store in tightly closed containersin a cool, well-ventilated area away from heat. Sources ofignition, such as smoking and open flames, are prohibitedwhere this chemical is used, handled, or stored in a mannerthat could create a potential fire or explosion hazard. Metalcontainers involving the transfer of 5 gallons or more ofthis chemical should be grounded and bonded. Drums mustbe equipped with self-closing valves, pressure vacuumbungs, and flame arresters. Use only nonsparking tools andequipment, especially when opening and closing containersof this chemical.

Shipping

UN 2735A mines, liquid, corrosive, n.o.s, or Polyamines, liquid, corrosive, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required. UN3267 Corrosive liquid, basic, organic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required.

Incompatibilities

Combustible; vapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides.

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