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(S)-(+)-5-(Hydroxymethyl)-2-pyrrolidinone p-toluenesulfonate

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(S)-(+)-5-(Hydroxymethyl)-2-pyrrolidinone p-toluenesulfonate Basic information

Product Name:
(S)-(+)-5-(Hydroxymethyl)-2-pyrrolidinone p-toluenesulfonate
Synonyms:
  • (S)-(+)-5-(HYDROXYMETHYL)-2-PYRROLIDINONE P-TOLUENESULFONATE
  • (S)-5-HYDROXYMETHYL-2-PYRROLIDINONE P-TOLUENESULFONATE
  • (-)-L-PYROGLUTAMOL P-TOLUENESULFONATE
  • 4-methylbenzenesulfonic acid [(2S)-5-oxo-2-pyrrolidinyl]methyl ester
  • (R)-Anabasine, >
  • (S)-(+)-5-(hydroxymethyl)-2-pyrrolidinone P-tolu
  • TOLUENE-4-SULFONIC ACID (S)-5-OXO-PYRROLIDIN-2-YLMETHYL ESTER
  • >98%ee
CAS:
51693-17-5
MF:
C12H15NO4S
MW:
269.32
Product Categories:
  • Chiral Building Blocks
  • Heterocyclic Building Blocks
  • Pyrrolidines
Mol File:
51693-17-5.mol
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(S)-(+)-5-(Hydroxymethyl)-2-pyrrolidinone p-toluenesulfonate Chemical Properties

Melting point:
124-128 °C (lit.)
alpha 
8.5 º (c=1 in ethanol)
Boiling point:
504.8±23.0 °C(Predicted)
Density 
1.275±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,2-8°C
pka
15.34±0.40(Predicted)
form 
Powder
color 
Colorless to beige
optical activity
[α]20/D +8.5°, c = 1 in ethanol
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29339980

MSDS

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(S)-(+)-5-(Hydroxymethyl)-2-pyrrolidinone p-toluenesulfonate Usage And Synthesis

Chemical Properties

colorless to beige powder

Uses

Serves as a building block in the synthesis of (R)- and (S)-diaminovaleric acids and of 5-azasemicorrin bidentate nitrogen ligands for enantioselective catalysis.

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