Basic information Reaction Safety Supplier Related

4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole

Basic information Reaction Safety Supplier Related

4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole Basic information

Product Name:
4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole
Synonyms:
  • 4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole
  • 4-(9-Anthracenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-1,3-benzoxaphosphole
  • 4-(ANTHRACEN-9-YL)-3-(T-BUTYL-2,3-DIHYDROBENZO[D][1,3]OXAPHOSPHOLE,98+%RAC-ANTPHOS
  • ZJ-0014
  • rac-AntPhos
  • 1,3-Benzoxaphosphole, 4-(9-anthracenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-
  • 4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole
  • 4-(9-Anthracenyl)-3-(tert-butyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole
CAS:
1268693-24-8
MF:
C25H23OP
MW:
370.42
Product Categories:
  • Achiral Phosphine
  • Aryl Phosphine
Mol File:
1268693-24-8.mol
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4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole Chemical Properties

Boiling point:
525.7±50.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
pale yellow
Sensitive 
air sensitive, store cold
InChI
InChI=1S/C25H23OP/c1-25(2,3)27-16-26-22-14-8-13-21(24(22)27)23-19-11-6-4-9-17(19)15-18-10-5-7-12-20(18)23/h4-15H,16H2,1-3H3
InChIKey
HKAWVLHXUZNLPP-UHFFFAOYSA-N
SMILES
O1C2=CC=CC(C3C4=CC=CC=C4C=C4C=3C=CC=C4)=C2P(C(C)(C)C)C1
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Safety Information

HS Code 
2931499090
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4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole Usage And Synthesis

Reaction

  1. Ligand/palladium catalyst for general Miyaura borylation reactions.
  2. Ligand/palladium catalyst for general and sterically demanding Suzuki-Miyaura cross-coupling reactions.
  3. Ligand/palladium catalyst for aryl-alkyl Suzuki-Miyaura cross-coupling reactions.
  4. Ligand/nickel catalyst for intramolecular reductive cyclization.
  5. Ligand/palladium catalyst for Dearomative cyclization.

4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphospholeSupplier

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