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Dioctyltin oxide

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Dioctyltin oxide Basic information

Product Name:
Dioctyltin oxide
Synonyms:
  • di-n-octyltinoxide98%
  • Dioctyltin oxide (DOTO)
  • TIB KAT 232
  • ViaCat 8201 (DOTO)
  • di-n-octyl-zinnoxyd
  • dioctyloxo-stannan
  • dioctyl-tioxide
  • oxodioctyl-stannan
CAS:
870-08-6
MF:
C16H34OSn
MW:
361.15
EINECS:
212-791-1
Product Categories:
  • Alkyl Metals
  • Classes of Metal Compounds
  • Grignard Reagents & Alkyl Metals
  • Sn (Tin) Compounds
  • Synthetic Organic Chemistry
  • Typical Metal Compounds
Mol File:
870-08-6.mol
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Dioctyltin oxide Chemical Properties

Melting point:
245-248°C (dec.)
Density 
1,3 g/cm3
vapor pressure 
<0.01 hPa (20 °C)
Flash point:
70°C
storage temp. 
Store below +30°C.
solubility 
Toluene (Slightly)
form 
Powder
color 
White
Specific Gravity
1.30
Water Solubility 
Insoluble
Boiling point:
230°C (1013 hPa)
Exposure limits
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
LogP
6 at 20℃
CAS DataBase Reference
870-08-6(CAS DataBase Reference)
EPA Substance Registry System
Stannane, dioctyloxo- (870-08-6)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26-24/25
RIDADR 
UN3146
WGK Germany 
WGK 2 water endangering
RTECS 
WH7620000
Autoignition Temperature
>100 °C
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29310095
Toxicity
LD50 orally in Rabbit: 2500 mg/kg

MSDS

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Dioctyltin oxide Usage And Synthesis

Chemical Properties

white to almost white crystalline powder. It is practically insoluble in water but soluble in organic solvents.

Uses

Dioctyltin oxide is used as a stabilizer and as a widely applicable catalyst, especially for esterification reactions, transesterification reactions and condensation reactions. It is slightly less reactive than dibutyltin oxide, but is not subject to as many regulatory restrictions, which is why it is increasingly used. Dioctyloxotin can also be used in various chemical synthesis such as in preparation of trinuclear seven-coordinated tin complexes, having possible antioxidant, and anti-inflammatory activity.

Application

Amorphous white solid available in various particle sizes with several uses:
widespread use in the aqueous cathodic electrodeposition of urethane coatings for automotive and industrial applications
active transesterification catalyst for methacrylate esters that are used in the water treatment market
high temperature transesterification reactions for the production of coating resins and specialty monomeric esters
intermediate for heat stabilizers

Flammability and Explosibility

Non flammable

Safety Profile

Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. See also TIN COMPOUNDS.

Dioctyltin oxide Preparation Products And Raw materials

Preparation Products

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